Urea postmodified in a metal-organic framework as a catalytically active hydrogen-bond-donating heterogeneous catalyst

被引：109

作者：

Dong, Xiao-Wu ^{[1
]}

Liu, Tao ^{[1
]}

Hu, Yong-Zhou ^{[1
]}

Liu, Xin-Yuan ^{[2
]}

Che, Chi-Ming ^{[3
,4
]}

机构：

[1] Zhejiang Univ, ZJU ENS Joint Lab Med Chem, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China

[2] South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Peoples R China

[3] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[4] Univ Hong Kong, State Key Lab Synthet Chem, Hong Kong, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 70期

基金：

中国博士后科学基金;

关键词：

D O I：

10.1039/c3cc42531b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New functionally diverse urea-derived MOF hydrogen-bond-donating heterogeneous catalysts were achieved via postsynthetic modification, which exhibit excellent catalytic activity and very broad substrate scopes for the Friedel-Crafts alkylation reactions.

引用

页码：7681 / 7683

页数：3

共 25 条

[21] Hydrogen Storage in Metal-Organic Frameworks [J].

Suh, Myunghyun Paik ;

Park, Hye Jeong ;

Prasad, Thazhe Kootteri ;

Lim, Dae-Woon .

CHEMICAL REVIEWS, 2012, 112 (02) :782-835

[22] Asymmetric catalysis by chiral hydrogen-bond donors [J].

Taylor, MS ;

Jacobsen, EN .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) :1520-1543

[23] Generating Reactive MILs: Isocyanate- and Isothiocyanate-Bearing MILs through Postsynthetic Modification [J].

Volkringer, Christophe ;

Cohen, Seth M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (27) :4644-4648

[24] Homochiral porous metal-organic framework for highly enantioselective heterogeneous asymmetric catalysis [J].

Wu, CD ;

Hu, A ;

Zhang, L ;

Lin, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (25) :8940-8941

[25] Homochiral Metal-Organic Frameworks for Asymmetric Heterogeneous Catalysis [J].

Yoon, Minyoung ;

Srirambalaji, Renganathan ;

Kim, Kimoon .

CHEMICAL REVIEWS, 2012, 112 (02) :1196-1231

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