New BODIPY derivatives as OFF-ON fluorescent chemosensor and fluorescent chemodosimeter for Cu2+:: Cooperative selectivity enhancement toward Cu2+

被引：362
|
作者：
Qi, X
Jun, EJ
Xu, L
Kim, SJ
Hong, JSJ
Yoon, YJ
Yoon, JY
机构：
[1] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea
[2] Ewha Womans Univ, Div Nano Sci, Seoul 120750, South Korea
[3] Seoul Natl Univ, Interdisciplinary Program Biochem Engn & Biotechn, Seoul 151742, South Korea
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 07期
关键词：
D O I：
10.1021/jo052542a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) derivatives (1 and 2) were synthesized as an "off-on" fluorescent chemosensor and fluorescent chemodosimeter for Cu2+ and Pb2+. Compound 1 displayed selective and large chelation enhanced fluorescence effects with Pb2+ and Cu2+ among the metal ions examined. On the other hand, compound 2, a fluorescent chemodosimeter, effectively recognized Cu2+ via a selective hydrolysis of the acetyl group.
引用
收藏
页码：2881 / 2884
页数：4
相关论文
共 50 条
  • [31] A Colorimetric and Fluorescent Chemosensor for Cu2+ Detection in Aqueous Solution
    Li, Lian-Qing
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (12) : 1854 - 1856
  • [32] Action of a fluorescent chemosensor for Cu2+ encapsulated in silica xerogel
    Klonkowski, AM
    Kledzik, K
    Ostaszewski, R
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 1999, 35 (1-2) : 165 - 171
  • [33] Coumarin-based 'turn-off' fluorescent chemosensor with high selectivity for Cu2+ in aqueous solution
    Xu, Wen-Jun
    Qi, De-Qiang
    You, Jin-Zong
    Hu, Fei-Fei
    Bian, Jia-Ying
    Yang, Chun-Xia
    Huang, Juan
    JOURNAL OF MOLECULAR STRUCTURE, 2015, 1091 : 133 - 137
  • [34] Colorimetric and fluorescent "on-off" chemosensor for Cu2+ in semi-aqueous medium
    Fegadea, Umesh
    Sahoo, Suban K.
    Attarde, Sanjay
    Singh, Narinder
    Kuwar, Anil
    SENSORS AND ACTUATORS B-CHEMICAL, 2014, 202 : 924 - 928
  • [35] Photoactive chemosensors 4:: a Cu2+ protein cavity mimicking fluorescent chemosensor for selective Cu2+ recognition
    Kaur, S
    Kumar, S
    TETRAHEDRON LETTERS, 2004, 45 (26) : 5081 - 5085
  • [36] A new Schiff-base type selective fluorescent chemosensor for Cu2+
    Li, Hong-Ge
    Yang, Zheng-Yin
    Qin, Dong-Dong
    INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (06) : 494 - 497
  • [37] New Meso-ortho-hydroxy-decorating Fluorescent ON-OFF Bodipy sensor to Cu2+
    Chen, Yuting
    Wang, Kang
    Jiang, Jianzhuang
    INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 68 : 9 - 12
  • [38] Coumarin-derivative-based off-on catalytic chemodosimeter for Cu2+ ions
    Kim, Mi Hee
    Jang, Hyun Hye
    Yi, Sujung
    Chang, Suk-Kyu
    Han, Min Su
    CHEMICAL COMMUNICATIONS, 2009, (32) : 4838 - 4840
  • [39] An "Off-On" Near-Infrared Fluorescent Probe for Cu2+ Detection in Living Cells
    Fang, Ru
    Ding, Xu
    Luo, Wen
    Hong, Chen
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (09) : 2949 - 2955
  • [40] A Highly Selective and High-Contrast Colorimetric "Off-On" Chemosensor for Cu2+ Based on Boron-Dipyrromethene (BODIPY) Derivatives
    Zhao Xiaolong
    Li Yuqing
    Guo Liangwu
    Ran Qiyuan
    Wu Huihui
    Zhang Zhen
    Su Yingpeng
    Zhou Pengxin
    Yan Na
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2022, 42 (11) : 3757 - 3765
12345