Ionic iridium complex coordinated with tetrathiafulvalene-fused phenanthroline ligand: Synthesis, photophysical, electrochemical and electrochemiluminescence properties

被引：12
|
作者：
Qin, Jie [1 ,3 ]
Deng, Sheng-Yuan [2 ,4 ]
Qian, Chen-Xi [3 ]
Li, Tian-Yi [3 ]
Ju, Huang-Xian [4 ]
Zuo, Jing-Lin [3 ]
机构：
[1] Shandong Univ Technol, Sch Life Sci, Zibo 255049, Peoples R China
[2] Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210094, Jiangsu, Peoples R China
[3] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[4] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Analyt Chem Life Sci, Nanjing 210093, Jiangsu, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 750卷
基金：
中国国家自然科学基金;
关键词：
Cationic iridium complex; Tetrathiafulvalene ligand; Photoluminescence; Electrochemiluminescence; ELECTRON-TRANSFER; REDOX; DONOR; 1ST; TTF; PHOSPHORESCENT; CHEMISTRY; STATES; GREEN;
D O I：
10.1016/j.jorganchem.2013.10.041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new cationic iridium(III) complex salt, [Ir(ppy)(2)(L)]PF6 (ppy = 2-phenylpyridine) (1), was synthesized by using tetrathiafulvalene fused 4',5'-dimethyldithiotetrathiafulvenyl[4,5-f][1,10]phenanthroline (L) as (NN)-N-boolean AND ancillary ligand. The photophysical, electrochemical and electrochemiluminescence (ECL) behavior of the complex are investigated. Complex 1 is found to be emissive at room temperature with the lambda(max) value at 607 nm. It is expected that this new luminescent complex 1 would be further explored for promising applications in functional emitting material. (C) 2013 Elsevier B. V. All rights reserved.
引用
收藏
页码：7 / 12
页数：6
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