Improved performance of sulfur cathode by an easy and scale-up coating strategy

被引:20
作者
Fang, Jing [1 ]
Qin, Furong [1 ]
Li, Jie [1 ]
Zhang, Kai [1 ]
Liu, Wenwen [1 ]
Wang, Mengran [1 ]
Yu, Fan [1 ]
Zhang, Liyuan [1 ]
机构
[1] Cent S Univ, Sch Met & Environm, Changsha 410083, Peoples R China
基金
中国国家自然科学基金;
关键词
Lithium sulfur battery; Sulfur cathode; Polysulfides; Improved performance; Super P; CARBON PAPER; LITHIUM; BATTERIES; CAPACITY; GRAPHENE; ELECTRODE; HYBRID;
D O I
10.1016/j.jpowsour.2015.06.153
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new fabricating process for high-performance sulfur cathode is proposed. The fabricating process relies on two-step coating technique: firstly, high sulfur content slurry is coated on the current collector. After drying, the electrode is coated with another slurry composed of Super P and binder. The sulfur electrode with relatively high sulfur content/loading of 60 wt%/2 mg cm(-2) discharges capacity of similar to 695 mAh g(-1) at 0.5 C after 100 cycling. This method is easy for industrialization and well controlled over the areal sulfur loading and mass, therefore it is efficient for fabricating high-performance Li-S batteries with high-energy density. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:265 / 270
页数:6
相关论文
共 40 条
[1]  
[Anonymous], 2014, ELECT J DIFF EQU, DOI DOI 10.1049/CP.2014.0129
[2]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[3]  
Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
[4]   Hydrothermal carbon-based nanostructured hollow spheres as electrode materials for high-power lithium-sulfur batteries [J].
Brun, Nicolas ;
Sakaushi, Ken ;
Yu, Linghui ;
Giebeler, Lars ;
Eckert, Juergen ;
Titirici, Magdalena M. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (16) :6080-6087
[5]   A Natural Carbonized Leaf as Polysulfide Diffusion Inhibitor for High-Performance Lithium-Sulfur Battery Cells [J].
Chung, Sheng-Heng ;
Manthiram, Arumugam .
CHEMSUSCHEM, 2014, 7 (06) :1655-1661
[6]   Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries [J].
Elazari, Ran ;
Salitra, Gregory ;
Garsuch, Arnd ;
Panchenko, Alexander ;
Aurbach, Doron .
ADVANCED MATERIALS, 2011, 23 (47) :5641-+
[7]   Expansion and shrinkage of the sulfur composite electrode in rechargeable lithium batteries [J].
He, Xiangming ;
Ren, Jianguo ;
Wang, Li ;
Pu, Weihua ;
Jiang, Changyin ;
Wan, Chunrong .
JOURNAL OF POWER SOURCES, 2009, 190 (01) :154-156
[8]   Functional, water-soluble binders for improved capacity and stability of lithium-sulfur batteries [J].
Lacey, Matthew J. ;
Jeschull, Fabian ;
Edstrom, Kristina ;
Brandell, Daniel .
JOURNAL OF POWER SOURCES, 2014, 264 :8-14
[9]   Structural changes of a Li/S rechargeable cell in Lithium Metal Polymer technology [J].
Lecuyer, Margaud ;
Gaubicher, Joel ;
Deschamps, Marc ;
Lestriez, Bernard ;
Brousse, Thierry ;
Guyomard, Dominique .
JOURNAL OF POWER SOURCES, 2013, 241 :249-254
[10]   Enhanced performance of lithium sulfur battery with self-assembly polypyrrole nanotube film as the functional interlayer [J].
Ma, Guoqiang ;
Wen, Zhaoyin ;
Wang, Qingsong ;
Shen, Chen ;
Peng, Peng ;
Jin, Jun ;
Wu, Xiangwei .
JOURNAL OF POWER SOURCES, 2015, 273 :511-516