Functionalized IRMOF-3: An Efficient Heterogeneous Catalyst for the Cycloaddition of Allyl Glycidyl Ether and CO2

被引：44

作者：

Kim, Yu-Jin ^{[1
]}

Park, Dae-Won ^{[1
]}

机构：

[1] Pusan Natl Univ, Div Chem & Biomol Engn, Pusan 609735, South Korea

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2013年 / 13卷 / 03期

基金：

新加坡国家研究基金会;

关键词：

Metal Organic Framework; F-IRMOF-3; Fast Precipitation; Cycloaddition; Carbon Dioxide; AGE; CARBON-DIOXIDE; IONIC LIQUIDS; CYCLIC CARBONATES; STYRENE CARBONATE; EPOXIDES; OXIDE; COPOLYMERIZATION; SYSTEM; OPTIMIZATION; FRAMEWORK;

D O I：

10.1166/jnn.2013.6878

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functionalized metal organic framework F-IRMOF-3 having quaternary ammonium group was prepared by a fast precipitation and solvothermal method. They showed good catalytic performance for the cycloaddition of allyl glycidyl ether (AGE) and carbon dioxide without any solvent. F-IRMOF-3 with a larger alkyl chain structure and more nucleophilic anion exhibited better reactivity for the cycloaddition reaction. The introduction of a defective ZnO to F-IRMOF-3 by the fast precipitation method becomes more advantageous than the conventional solvothermal method for the cycloaddition reaction due to acid-base bifunctional active sites. The F-IRMOF-3 can be easily recovered and reused without any considerable loss of initial activity.

引用

页码：2307 / 2312

页数：6

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