Functionalized IRMOF-3: An Efficient Heterogeneous Catalyst for the Cycloaddition of Allyl Glycidyl Ether and CO2

被引：44
|
作者：
Kim, Yu-Jin [1 ]
Park, Dae-Won [1 ]
机构：
[1] Pusan Natl Univ, Div Chem & Biomol Engn, Pusan 609735, South Korea
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2013年 / 13卷 / 03期
基金：
新加坡国家研究基金会;
关键词：
Metal Organic Framework; F-IRMOF-3; Fast Precipitation; Cycloaddition; Carbon Dioxide; AGE; CARBON-DIOXIDE; IONIC LIQUIDS; CYCLIC CARBONATES; STYRENE CARBONATE; EPOXIDES; OXIDE; COPOLYMERIZATION; SYSTEM; OPTIMIZATION; FRAMEWORK;
D O I：
10.1166/jnn.2013.6878
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Functionalized metal organic framework F-IRMOF-3 having quaternary ammonium group was prepared by a fast precipitation and solvothermal method. They showed good catalytic performance for the cycloaddition of allyl glycidyl ether (AGE) and carbon dioxide without any solvent. F-IRMOF-3 with a larger alkyl chain structure and more nucleophilic anion exhibited better reactivity for the cycloaddition reaction. The introduction of a defective ZnO to F-IRMOF-3 by the fast precipitation method becomes more advantageous than the conventional solvothermal method for the cycloaddition reaction due to acid-base bifunctional active sites. The F-IRMOF-3 can be easily recovered and reused without any considerable loss of initial activity.
引用
收藏
页码：2307 / 2312
页数：6
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