Rhodium-catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C-H Bond Cleavage

被引：57
|
作者：
Yokoyama, Yuki [1 ]
Unoh, Yuto [1 ,2 ]
Bohmann, Rebekka Anna [1 ,3 ]
Satoh, Tetsuya [1 ,2 ,4 ]
Hirano, Koji [1 ]
Bolm, Carsten [3 ]
Miura, Masahiro [1 ]
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] ACT C, JST, Kawaguchi, Saitama 3320012, Japan
[3] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
[4] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan
来源：
CHEMISTRY LETTERS | 2015年 / 44卷 / 08期
关键词：
OXIDATIVE ANNULATION; DIRECT ARYLATION; ALKENYLATION; SULFOXIDES; SULFOXIMINES; ACTIVATION; THIOETHERS; FUNCTIONALIZATIONS; OLEFINATION; INHIBITORS;
D O I：
10.1246/cl.150444
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rhodium-catalyzed direct coupling of benzothioamides with alkenes proceeds smoothly involving ortho-C-H bond cleavage. The thioamides also couple with alkynes under similar conditions accompanied by desulfurization and C-N bond cleavage to produce indenone derivatives.
引用
收藏
页码：1104 / 1106
页数：3
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