Phase Transfer Directed Synthesis of Hollow Zeolitic Imidazolate Frameworks-67 Nanocages

被引：19
|
作者：
Yu, Bo [1 ,2 ]
Zhang, Dejiang [1 ,2 ]
Du, Shichao [1 ,2 ]
Wang, Yan [1 ,2 ]
Chen, Mingyang [1 ,2 ]
Hou, Jie [1 ,2 ]
Xu, Shijie [1 ,2 ]
Wu, Songgu [1 ,2 ]
Gong, Junbo [1 ,2 ]
机构：
[1] Tianjin Univ, Sch Chem Engn & Technol, State Key Lab Chem Engn, Tianjin 300072, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2017年 / 17卷 / 01期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORKS; SELF-TEMPLATE SYNTHESIS; CORE-SHELL; HETEROSTRUCTURES; PHOTOCATALYSIS; MICROSPHERES; NANOSPHERES; SELECTIVITY; STABILITY; CATALYSIS;
D O I：
10.1021/acs.cgd.6b01392
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cubic zeolitic imidazolate frameworks (ZIFs) nano cage was prepared by using a nrultitemplate and phase transfer directed method. Phase transfer of aqueous metal ions on the interface of cubic Cu2O template was achieved by coordinating etching and precipitating process, in which cubic morphology was preserved and hollow metal Oxide nanocages were obtained due to the removal of templates. Therefore, cubic ZIFs nanocages could be formed by the transformation of metal oxide cages, which was a self-template transforming process. The former metal oxide nanocages will not only be the template, but also the metal source for the construction of ZIFs as well. This phase transfer directed method will offer a further development of porous metal organic frameworks with functional hollow structure.
引用
收藏
页码：3 / 6
页数：4
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