The first structurally characterized coordination compound containing direct Al-Cr bonding:: Cp*Al-Cr(CO)5

被引：68
|
作者：
Yu, Q [1 ]
Purath, A [1 ]
Donchev, A [1 ]
Schnöckel, H [1 ]
机构：
[1] Univ Karlsruhe TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 584卷 / 01期
关键词：
aluminium(I) compounds; cyclopentadiene; Al-Cr bonding; crystal structure; chromiumpentacarbonyl;
D O I：
10.1016/S0022-328X(99)00100-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In order to investigate the bonding of the carbene-like ligand AlCp* towards a has been prepared starting from Cr(CO)SCOT and AlCp*. With the help of its cr ab initio calculations, the Al-Cr bonding is discussed. The strong reducing al towards the chromium atom and finally to the CO ligands. (C) 1993 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：94 / 97
页数：4
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