The first structurally characterized coordination compound containing direct Al-Cr bonding:: Cp*Al-Cr(CO)5

被引：68
|
作者：
Yu, Q [1 ]
Purath, A [1 ]
Donchev, A [1 ]
Schnöckel, H [1 ]
机构：
[1] Univ Karlsruhe TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 584卷 / 01期
关键词：
aluminium(I) compounds; cyclopentadiene; Al-Cr bonding; crystal structure; chromiumpentacarbonyl;
D O I：
10.1016/S0022-328X(99)00100-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In order to investigate the bonding of the carbene-like ligand AlCp* towards a has been prepared starting from Cr(CO)SCOT and AlCp*. With the help of its cr ab initio calculations, the Al-Cr bonding is discussed. The strong reducing al towards the chromium atom and finally to the CO ligands. (C) 1993 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：94 / 97
页数：4
相关论文
共 50 条
  • [1] Investigation of the Al-Cr γ-range
    Grushko, B
    Kowalska-Strzeciwilk, E
    Przepiórzynski, B
    Surowiec, M
    JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 402 (1-2) : 98 - 104
  • [2] Investigation of the Al-Cr γ-range
    Grushko, B.
    Kowalska-Strzȩciwilk, E.
    Przepiórzyński, B.
    Surowiec, M.
    Journal of Alloys and Compounds, 2005, 402 (1-2): : 98 - 104
  • [3] Al-Cr (Aluminum-Chromium)
    Okamoto, H.
    JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION, 2008, 29 (01) : 112 - 113
  • [4] Thermodynamic modeling of the Al-Cr system
    Liang, Yu
    Guo, Cuiping
    Li, Changrong
    Du, Zhenmin
    JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 460 (1-2) : 314 - 319
  • [5] Phase equilibria in the Al-Cr system
    Audier, M., 1600, Elsevier Science S.A., Lausanne (220): : 1 - 2
  • [6] Thermodynamic modeling of the Al-Cr system
    Liang, Yu
    Guo, Cuiping
    Li, Changrong
    Du, Zhenmin
    Journal of Alloys and Compounds, 2008, 460 (1-2): : 314 - 319
  • [7] Al-Cr (Aluminum-Chromium)
    H. Okamoto
    Journal of Phase Equilibria and Diffusion, 2008, 29 : 112 - 113
  • [8] VISCOSITY OF LIQUID AL-CR ALLOYS
    LEVIN, ES
    AYUSHINA, GD
    GELD, PV
    RUSSIAN METALLURGY-METALLY-USSR, 1970, (03): : 65 - &
  • [9] SYNTHESIS OF AL-CR INTERMETALLIC CRYSTALS
    RAMON, JJ
    SHECHTMAN, D
    DIRNFELD, SF
    SCRIPTA METALLURGICA ET MATERIALIA, 1990, 24 (06): : 1087 - 1091
  • [10] PRECIPITATION IN AL-MN AND AL-CR ALLOYS
    KEDVES, FJ
    HORDOS, M
    SCHUSZTER, F
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1976, 38 (02): : K123 - K126
12345