Selective C-O Coupling Reaction of N-Methoxy Arylamides and Arylboronic Acids Catalyzed by Copper Salt

被引：6

作者：

Wang, Ying ^{[1
]}

Xie, Huilin ^{[1
]}

Liu, Kunming ^{[1
]}

Li, Jinhui ^{[1
]}

Liu, Jin-Biao ^{[1
]}

机构：

[1] Jiangxi Univ Sci & Technol, Jiangxi Prov Key Lab Funct Mol Mat Chem, 86 Hongqi Rd, Ganzhou 341000, Peoples R China

来源：

CATALYSTS | 2022年 / 12卷 / 10期

基金：

中国国家自然科学基金;

关键词：

copper catalyzed; N-methoxy amides; selective C-O cross-coupling; aryl-N-methoxy arylimides; BORONIC ACIDS; ROOM-TEMPERATURE; ACYCLIC AMIDES; ACYL; CLEAVAGE; BONDS;

D O I：

10.3390/catal12101278

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein, we report a copper-catalyzed C-O cross-coupling of N-methoxy amides and arylboronic acids for the synthesis of aryl-N-methoxy arylimides. The fully selective O-arylation of the N-methoxy amides is found to be greatly prompted by the inexpensive and commercially available CuI. The reaction conditions tolerate a variety of functional groups and promote different reactivities depending on the electronic and steric properties of the distorted substrates.

引用

页数：10

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