Studies on intramolecular hydrogen bonding of 1,1'-bis[N-formyl-N'-p-chlorophenylthiourea]ferrocene

被引：20

作者：

Yuan, YF ^{[1
]}

Ye, SM ^{[1
]}

Zhang, LY ^{[1
]}

Wang, B ^{[1
]}

Xu, YM ^{[1
]}

Wang, JT ^{[1
]}

Wang, HG ^{[1
]}

机构：

[1] NANKAI UNIV,CENT LAB,TIANJIN 300071,PEOPLES R CHINA

来源：

INORGANICA CHIMICA ACTA | 1997年 / 256卷 / 02期

基金：

中国国家自然科学基金;

关键词：

ferrocene complexes; acyl thiourea complexes; hydrogen bonding; crystal structures;

D O I：

10.1016/S0020-1693(96)05438-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,1'-Bis[N-formyl-N'-p-chlorophenylthiourea]ferrocene was synthesized through the reaction of 1,1'-bis[formylisothiocyanate]ferrocene with p-chloroaniline. Its H-1 NMR, IR and mass spectra were studied. A single crystal structure determination showed that there are two intramolecular hydrogen bonds between the carbonyl group and N'-H of each N'H-C(S)-NH-C(O) moiety. They form two parallel planar six-membered rings. In addition, the hydrogen bonding rings are basically in the same plane with the Cp rings to which they are attached. This highlights its property in molecular recognition.

引用

页码：313 / 318

页数：6

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