Experimental investigations for recycling of silicon and glass from waste photovoltaic modules

被引:244
作者
Kang, Sukmin [1 ,2 ]
Yoo, Sungyeol [1 ]
Lee, Jina [1 ]
Boo, Bonghyun [2 ]
Ryu, Hojin [1 ]
机构
[1] Korea Res Inst Chem Technol, Energy Mat Res Ctr, Taejon 305600, South Korea
[2] Chungnam Natl Univ, Dept Chem, Taejon 305764, South Korea
关键词
Photovoltaic module; Ethylene vinyl acetate; Etching solution; Silicon; Recycling; SOLAR; FEEDSTOCK;
D O I
10.1016/j.renene.2012.04.030
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This paper reports a new procedure for the recovery of resources from waste photovoltaic modules. The tempered glass was recovered using organic solvents. The metal impurities were removed by applying a chemical etching solution on the surface of the PV cell. We offer a much more efficient approach for recycling PV cells than the conventional method. The highest yield of silicon recovered was 86% when the PV cell was placed in the chemical etching solution for 20 min, along with the surfactant, which accounted for 20% of the total solution's weight at room temperature. This investigation showed that a high yield of pure silicon with purity of 99.999% could be obtained. The recovered pure silicon from waste PV modules would be contributed to the solution of several problems such as the supply of silicon, manufacturing costs, and end-of-life management of PV modules. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:152 / 159
页数:8
相关论文
共 23 条
  • [1] Aspects of the thermal oxidation of ethylene vinyl acetate copolymer
    Allen, NS
    Edge, M
    Rodriguez, M
    Liauw, CM
    Fontan, E
    [J]. POLYMER DEGRADATION AND STABILITY, 2000, 68 (03) : 363 - 371
  • [2] [Anonymous], RENEW ENERGY WORLD M
  • [3] A novel approach for the recycling of thin film photovoltaic modules
    Berger, Wolfgang
    Simon, Franz-Georg
    Weimann, Karin
    Alsema, Erik A.
    [J]. RESOURCES CONSERVATION AND RECYCLING, 2010, 54 (10) : 711 - 718
  • [4] Bruton T.M., 1994, P 12 EC PHOT SOL EN, P303
  • [5] CURRENT STATUS - PRODUCTION OF HIGH-EFFICIENCY MONOCRYSTALLINE SILICON SOLAR-CELLS
    BRUTON, TM
    [J]. RENEWABLE ENERGY, 1995, 6 (03) : 299 - 302
  • [6] Choo ST, 2003, THEORIES APPL CHEM E, V9, P2348
  • [7] Experimental study on PV module recycling with organic solvent method
    Doi, T
    Tsuda, I
    Unagida, H
    Murata, A
    Sakuta, K
    Kurokawa, K
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 67 (1-4) : 397 - 403
  • [8] Analysis of micro segregation in RF-heated float zone growth of silicon-comparison to the radiation-heated process
    Dold, P
    [J]. JOURNAL OF CRYSTAL GROWTH, 2004, 261 (01) : 1 - 10
  • [9] Recycling silicon solar cell waste in cement-based systems
    Fernandez, Lucia J.
    Ferrer, R.
    Aponte, D. F.
    Fernandez, P.
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (07) : 1701 - 1706
  • [10] End-of-life management and recycling of PV modules
    Fthenakis, VM
    [J]. ENERGY POLICY, 2000, 28 (14) : 1051 - 1058