Experimental investigations for recycling of silicon and glass from waste photovoltaic modules

被引:256
作者
Kang, Sukmin [1 ,2 ]
Yoo, Sungyeol [1 ]
Lee, Jina [1 ]
Boo, Bonghyun [2 ]
Ryu, Hojin [1 ]
机构
[1] Korea Res Inst Chem Technol, Energy Mat Res Ctr, Taejon 305600, South Korea
[2] Chungnam Natl Univ, Dept Chem, Taejon 305764, South Korea
关键词
Photovoltaic module; Ethylene vinyl acetate; Etching solution; Silicon; Recycling; SOLAR; FEEDSTOCK;
D O I
10.1016/j.renene.2012.04.030
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This paper reports a new procedure for the recovery of resources from waste photovoltaic modules. The tempered glass was recovered using organic solvents. The metal impurities were removed by applying a chemical etching solution on the surface of the PV cell. We offer a much more efficient approach for recycling PV cells than the conventional method. The highest yield of silicon recovered was 86% when the PV cell was placed in the chemical etching solution for 20 min, along with the surfactant, which accounted for 20% of the total solution's weight at room temperature. This investigation showed that a high yield of pure silicon with purity of 99.999% could be obtained. The recovered pure silicon from waste PV modules would be contributed to the solution of several problems such as the supply of silicon, manufacturing costs, and end-of-life management of PV modules. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:152 / 159
页数:8
相关论文
共 23 条
[1]   Aspects of the thermal oxidation of ethylene vinyl acetate copolymer [J].
Allen, NS ;
Edge, M ;
Rodriguez, M ;
Liauw, CM ;
Fontan, E .
POLYMER DEGRADATION AND STABILITY, 2000, 68 (03) :363-371
[2]  
[Anonymous], RENEW ENERGY WORLD M
[3]   A novel approach for the recycling of thin film photovoltaic modules [J].
Berger, Wolfgang ;
Simon, Franz-Georg ;
Weimann, Karin ;
Alsema, Erik A. .
RESOURCES CONSERVATION AND RECYCLING, 2010, 54 (10) :711-718
[4]  
Bruton T.M., 1994, P 12 EC PHOT SOL EN, P303
[5]   CURRENT STATUS - PRODUCTION OF HIGH-EFFICIENCY MONOCRYSTALLINE SILICON SOLAR-CELLS [J].
BRUTON, TM .
RENEWABLE ENERGY, 1995, 6 (03) :299-302
[6]  
Choo ST, 2003, THEORIES APPL CHEM E, V9, P2348
[7]   Experimental study on PV module recycling with organic solvent method [J].
Doi, T ;
Tsuda, I ;
Unagida, H ;
Murata, A ;
Sakuta, K ;
Kurokawa, K .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 67 (1-4) :397-403
[8]   Analysis of micro segregation in RF-heated float zone growth of silicon-comparison to the radiation-heated process [J].
Dold, P .
JOURNAL OF CRYSTAL GROWTH, 2004, 261 (01) :1-10
[9]   Recycling silicon solar cell waste in cement-based systems [J].
Fernandez, Lucia J. ;
Ferrer, R. ;
Aponte, D. F. ;
Fernandez, P. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (07) :1701-1706
[10]   End-of-life management and recycling of PV modules [J].
Fthenakis, VM .
ENERGY POLICY, 2000, 28 (14) :1051-1058