Feasibility of Using Near-Infrared Spectroscopy for Rapid Quantification of 17β-Estradiol Sorption Coefficients in Soil

被引:7
|
作者
Singh, Baljeet [1 ]
Malley, Diane F. [2 ]
Farenhorst, Annemieke [1 ]
Williams, Phil [2 ]
机构
[1] Univ Manitoba, Dept Soil Sci, Winnipeg, MB R3T 2N2, Canada
[2] PDK Projects Inc, Nanaimo, BC V9V 1L6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
17; beta-estradiol; near-infrared spectroscopy; soil organic carbon; soil profiles; sorption; DIFFUSE-REFLECTANCE SPECTROSCOPY; ORGANIC-CARBON FRACTIONS; 17; BETA-ESTRADIOL; ESTROGENIC HORMONES; MIDINFRARED SPECTROSCOPY; AGRICULTURAL SOILS; POULTRY LITTER; CONTAMINANTS; TERRAIN; RUNOFF;
D O I
10.1021/jf302492w
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Livestock manure contains natural steroid hormones, with the most potent being 17 beta-estradiol. The transport of steroid hormones from agricultural fields to adjacent water bodies can result in 17 beta-estradiol environmental contamination impacting aquatic organisms. Sorption coefficients are useful input into models that estimate risk of water contamination. The feasibility of applying near-infrared spectroscopy (NIRS) for determining sorption coefficients of 17 beta-estradiol in soil was investigated for two irregular undulating to hummocky terrain landscapes in Manitoba and Saskatchewan, Canada. A total of 609 soil samples in 140 soil profiles were collected from several horizons to a depth of 1 m. Air-dried and sieved (2 mm) soil samples were analyzed for soil organic carbon (SOC), soil pH, and soil texture. Sorption coefficients of 17 beta-estradiol were determined by a batch equilibrium process. Spectral data were collected from soil samples (25 g) using two instruments, the 45VISNIR Zeiss Corona (wavelength range 700-1690 nm) and the Foss NIRSystems 6500 (wavelength range 1100-2500 nm). Regardless of the site and instrument, the predictive models were excellent for both SOC and 17 beta-estradiol sorption coefficients. The data thus generated can be used as input parameters in fate models for efficient risk assessments and decision-making programs for environmental safety where soils are at risk of receiving inputs of 17 beta-estradiol. Calibration results for soil pH were also adequate with Corona outperforming the Foss instrument. Soil texture predictions were relatively unsuccessful regardless of the instrument and site.
引用
收藏
页码:9948 / 9953
页数:6
相关论文
共 50 条
  • [1] Rapid prediction of atrazine sorption in soil using visible near-infrared spectroscopy
    Shan, Ruifeng
    Chen, Ya
    Meng, Lingchuan
    Li, Hongyang
    Zhao, Zhongqiang
    Gao, Mingze
    Sun, Xiaoyin
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2020, 224
  • [2] A feasibility quantification study of capsaicin content in chili powder for rapid evaluation using near-infrared reflectance spectroscopy
    Jing, Bowen
    Song, Wensheng
    Gao, Xin
    He, Ke
    Sun, Qinming
    Tang, Xiuying
    JOURNAL OF FOOD MEASUREMENT AND CHARACTERIZATION, 2023, 17 (05) : 4405 - 4414
  • [3] A feasibility quantification study of capsaicin content in chili powder for rapid evaluation using near-infrared reflectance spectroscopy
    Bowen Jing
    Wensheng Song
    Xin Gao
    Ke He
    Qinming Sun
    Xiuying Tang
    Journal of Food Measurement and Characterization, 2023, 17 : 4405 - 4414
  • [4] Feasibility study for the rapid determination of the amylose content in starch by near-infrared spectroscopy
    Fertig, CC
    Podczeck, F
    Jee, RD
    Smith, MR
    EUROPEAN JOURNAL OF PHARMACEUTICAL SCIENCES, 2004, 21 (2-3) : 155 - 159
  • [5] Rapid detection of microplastics in feeds using near-infrared spectroscopy
    Masoero, Giorgio
    Barbera, Salvatore
    Kaihara, Hatsumi
    Mabrouki, Sabah
    Patrucco, Sara Glorio
    Abid, Khalil
    Tassone, Sonia
    ACTA IMEKO, 2024, 13 (02): : 10 - 10
  • [6] Feasibility of monitoring acetic acid process using near-infrared spectroscopy
    Chung, H
    Ku, MS
    VIBRATIONAL SPECTROSCOPY, 2003, 31 (01) : 125 - 131
  • [7] Feasibility of Near-Infrared Spectroscopy for Rapid Detection of Available Nitrogen in Vermiculite Substrates in Desert Facility Agriculture
    Zhao, Pengfei
    Xing, Jianfei
    Hu, Can
    Guo, Wensong
    Wang, Long
    He, Xiaowei
    Xu, Zhengxin
    Wang, Xufeng
    AGRICULTURE-BASEL, 2022, 12 (03):
  • [8] A study on the use of near-infrared spectroscopy for the rapid quantification of major compounds in Tanreqing injection
    Li, Wenlong
    Cheng, Zhiwei
    Wang, Yuefei
    Qu, Haibin
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 101 : 1 - 7
  • [9] FEASIBILITY OF RAPID DIAGNOSIS OF COLORECTAL CANCER BY NEAR-INFRARED SPECTROSCOPY AND SUPPORT VECTOR MACHINE
    Chen, Hui
    Tan, Chao
    Wu, Hegang
    Lin, Zan
    Wu, Tong
    ANALYTICAL LETTERS, 2014, 47 (15) : 2580 - 2593
  • [10] Rapid crude oil analysis using near-infrared reflectance spectroscopy
    Long, Jian
    Wang, Kai
    Yang, Minglei
    Zhong, Weimin
    PETROLEUM SCIENCE AND TECHNOLOGY, 2019, 37 (03) : 354 - 360