Chiral induction controlled by aggregation of organometallics:: trifluoromethylated aminoalcohols for chiral ligands in Et2Zn alkylation of benzaldehyde

被引：25

作者：

Katagiri, T ^{[1
]}

Fujiwara, Y ^{[1
]}

Takahashi, S ^{[1
]}

Ozaki, N ^{[1
]}

Uneyama, K ^{[1
]}

机构：

[1] Okayama Univ, Dept Appl Chem, Okayama 7008530, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 09期

关键词：

D O I：

10.1039/b201238c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral induction in the reaction of Et2Zn with PhCHO by fluorinated chiral amino alcohols was correlated to the extent of aggregation of Et2Zn species, which was estimated by manometric study.

引用

页码：986 / 987

页数：2

共 39 条

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