Kinetics and mechanism of the liquid-phase reaction of 2,4-dinitrotoluene with ozone in the presence of manganese(II) acetate

被引：0

作者：

Galstyan, A. G. ^{[1
]}

Lysak, V. V. ^{[1
]}

Galstyan, G. A. ^{[1
]}

机构：

[1] East Ukrainian Natl Univ, Inst Chem Technol, UA-93009 Rubezhnoye, Luhansk Oblast, Ukraine

来源：

KINETICS AND CATALYSIS | 2013年 / 54卷 / 06期

关键词：

Manganese; Acetic Anhydride; Ozonolysis; Dielectric Barrier Discharge; Peroxy Radical;

D O I：

10.1134/S0023158413060050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics and the mechanism of the liquid-phase oxidation of 2,4-dinitrotoluene with ozone in the presence of manganese(II) acetate have been investigated. The major products of 2,4-dinitrotoluene oxidation with ozone in acetic anhydride are 2,4-dinitrobenzyl acetate (65.8%) and 2,4-dinitrobenzylidene diacetate (18.8%). The effect of the manganese(II) acetate concentration on the selectivity of substrate oxidation at the methyl group is reported. A redox catalysis mechanism providing an explanation to experimental data is considered.

引用

页码：686 / 690

页数：5

共 5 条

[1] Kinetics and mechanism of the liquid-phase reaction of 2,4-dinitrotoluene with ozone in the presence of manganese(II) acetate
A. G. Galstyan
V. V. Lysak
G. A. Galstyan
Kinetics and Catalysis, 2013, 54 : 686 - 690
[2] Oxidation of 2,4-dinitrotoluene with ozone in the presence of a stop reagent
A. G. Galstyan
V. V. Lysak
G. A. Galstyan
Russian Journal of Applied Chemistry, 2014, 87 : 31 - 35
[3] Kinetics and mechanism of the ozone reaction with cyclohexane in liquid phase
Anachkov, M. P.
Karakashkova, P. A.
Georgiev, V. F.
Rakovsky, S. K.
Minchev, L. S.
Batakliev, T. T.
BULGARIAN CHEMICAL COMMUNICATIONS, 2017, 49 : 38 - 44
[4] Study of reaction of isomeric acetoxytoluenes with ozone in liquid phase in the presence of manganese bromide catalyst
A. G. Galstyan
A. A. Sedykh
Russian Journal of General Chemistry, 2010, 80 : 948 - 952
[5] Study of reaction of isomeric acetoxytoluenes with ozone in liquid phase in the presence of manganese bromide catalyst
Galstyan, A. G.
Sedykh, A. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2010, 80 (05) : 948 - 952

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