Y8O(OH)15(CO3)3Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework

被引：50

作者：

Zhang, Yiting ^{[1
]}

Long, Ying ^{[1
]}

Dong, Xuehua ^{[1
]}

Wang, Lei ^{[2
]}

Huang, Ling ^{[2
]}

Zeng, Hongmei ^{[1
]}

Lin, Zhien ^{[1
]}

Wang, Xin ^{[1
]}

Zou, Guohong ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China

[2] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610068, Sichuan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 31期

基金：

中国国家自然科学基金;

关键词：

ALUMINOBORATE OPEN-FRAMEWORK; 2ND-HARMONIC GENERATION; BERYLLIUM-FREE; NONCENTROSYMMETRIC MATERIALS; FLUORIDE CARBONATE; CRYSTALS; DESIGN; NITRATE; RB;

D O I：

10.1039/c9cc00581a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel compound with four mixed anions, Y8O(OH)(15)(CO3)(3)Cl, exhibiting an infrequent three-dimensional (3-D) inorganic cationic framework, has been successfully designed and synthesized by introducing -conjugated planar triangular CO3 groups and chloride anions into a rare earth oxide system, which exhibits good balance among its wide UV transmission range, large second harmonic generation (SHG) coefficient and suitable birefringence to meet the phase-matching condition, indicating that the titled compound is a promising short-wave UV nonlinear optical material.

引用

页码：4538 / 4541

页数：4