Ruthenium-Catalyzed Synthesis of Functionalized 1,3-Dienes

被引：24

作者：

Achard, Mathieu ^{[1
]}

Derrien, Nolwenn ^{[1
]}

Zhang, Hui-Jun ^{[1
]}

Demerseman, Bernard ^{[1
]}

Bruneau, Christian ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR Sci Chim Catalyse & Organomet 6226, F-35042 Rennes, France

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 01期

关键词：

ALLYLIC ALKYLATION; NUCLEOPHILIC-SUBSTITUTION; ENYNE METATHESIS; ALLYLATION; COMPLEXES; ALKYNE; ETHYLENE;

D O I：

10.1021/ol8023488

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Functionalized 1,3-diene derivatives have been prepared by regioselective allylation of various nucleophiles with 1,3-dienic carbonates In the presence of a (N,O-carboxylate) allylruthenium precatalyst.

引用

页码：185 / 188

页数：4

共 37 条

[1] [Anonymous], RUTHENIUM ORGANIC SY
[2] Enantioselective and regioselective ruthenium-catalyzed decarboxylative etherification of allyl aryl carbonates
Austeri, Martina
Linder, David
Lacour, Jerome
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (19) : 5737 - 5741
[3] BRUNEAU C, 2008, E EROS, DOI DOI 10.1002/047084289X.RN00810
[4] Pentamethylcyclopentadienyl-ruthenium catalysts for regio- and enantioselective allylation of nucleophiles
Bruneau, Christian
Renaud, Jean-Luc
Demerseman, Bernard
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (20) : 5178 - 5187
[5] Ruthenium-catalyzed stereospecific decarboxylative allylation of non-stabilized ketone enolates
Burger, EC
Tunge, JA
[J]. CHEMICAL COMMUNICATIONS, 2005, (22) : 2835 - 2837
[6] Microwave-assisted ethylene-alkyne cross-metathesis:: synthesis of chiral 2-(N-1-acetyl-1-arylmethyl)-1,3-butadienes
Castagnolo, D
Renzulli, ML
Galletti, E
Corelli, F
Botta, M
[J]. TETRAHEDRON-ASYMMETRY, 2005, 16 (17) : 2893 - 2896
[7] Alkenol-alkyne cross metathesis
Clark, Daniel A.
Clark, Joseph R.
Diver, Steven T.
[J]. ORGANIC LETTERS, 2008, 10 (10) : 2055 - 2058
[8] REACTIONS OF COORDINATED LIGANDS .34. SYNTHESIS, STRUCTURE, AND REACTIVITY OF CATIONIC DIENERUTHENIUM COMPLEXES - CRYSTAL-STRUCTURES OF "[RU(ETA-4-C6H8)(CO)(ETA-C5H5)][BF4] AND [RU(ETA3-C6H9)(CO)(ETA-C5H5)]
CROCKER, M
GREEN, M
MORTON, CE
NAGLE, KR
ORPEN, AG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (10): : 2145 - 2153
[9] Enyne metathesis (enyne bond reorganization)
Diver, ST
Giessert, AJ
[J]. CHEMICAL REVIEWS, 2004, 104 (03) : 1317 - 1382
[10] STRUCTURE AND CHEMISTRY OF THE COMPLEX TETRAKIS(ETA-5-PENTAMETHYLCYCLOPENTADIENYL)TETRAKIS(MU-3-CHLORO)-TETRARUTHENIUM(II) - A USEFUL PRECURSOR TO (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(0), (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(II), AND (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(IV) COMPLEXES
FAGAN, PJ
MAHONEY, WS
CALABRESE, JC
WILLIAMS, ID
[J]. ORGANOMETALLICS, 1990, 9 (06) : 1843 - 1852

← 1 2 3 4 →