TR-FTIR study of the reaction CH2((X)over-tilde 3B1)+NO

被引：2
|
作者：
Yang, JX
Su, HM
Mao, WT
Zhong, JX
Kang, FA [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, State Key Lab Mol React Chem, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China
来源：
ACTA PHYSICO-CHIMICA SINICA | 1999年 / 15卷 / 07期
关键词：
CH2((X)over-tilde B-3(1)); state-specific reaction; TR-FTIR; NO;
D O I：
10.3866/PKU.WHXB19990712
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction of methylene radicals in their B-3(1) electronic ground state with molecular NO was studied. Pure CH2((X) over tilde B-3(1)) radicals were produced by UV photolysis of ketene at 351 nm, The products were measured by Time-Resolved Fourier Transform Infrared (TR-FTIR) spectrometer, CO,OH,NH2 and HOCN or its isomer HNCO were found as primary products and several possible channels of this reaction were suggested.
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页码：643 / 646
页数：4
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