Concise Synthesis of Goniothalesdiol A

被引：1

作者：

Zeng, Ping Li ^{[1
]}

Zhou, Junhui ^{[2
]}

Yang, Xuechao ^{[1
]}

Wang, Dong ^{[2
]}

Dong, Zhibing ^{[3
]}

机构：

[1] Zhejiang Pharmaceut Coll, Sch Pharmaceut Engn, Ningbo 315100, Zhejiang, Peoples R China

[2] Zhejiang Pharmaceut Coll, Sch Basic Sci, Ningbo 315100, Zhejiang, Peoples R China

[3] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430073, Peoples R China

来源：

LETTERS IN ORGANIC CHEMISTRY | 2022年 / 19卷 / 12期

关键词：

Total synthesis; goniothalesdiol A; styryllactone; L-erythrose; Wacker oxidation; Wittig olefination-Michael addition; DERIVATIVES;

D O I：

10.2174/1570178619666220408121439

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A concise and efficient synthesis of styryllactone derivative, goniothalesdiol A, has been achieved in the six longest linear steps with 17.7% overall yield. The key steps of our synthesis involved PdCl2-mediated Wacker-type oxidative cyclisation and one-pot tandem Wittig olefination-Michael addition.

引用

页码：1145 / 1148

页数：4

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