Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-Organic Cd(II) Coordination Polymer Based on Helical Units

被引：0

作者：

Li, Hai-Hua ^{[1
]}

Zhang, Peng ^{[1
]}

Pu, Jia-Yi ^{[1
]}

Zhao, Yu-Ying ^{[1
]}

Mei, Chong-Zhen ^{[1
]}

机构：

[1] North China Univ Water Conservancy & Elect Power, Inst Environm & Municipal Engn, Zhengzhou 450011, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2013年 / 68卷 / 02期

关键词：

4-Methylphthalic Acid; Cd(II) Coordination Polymer; Double-helical Chain; Fluorescence; SUPRAMOLECULAR COMPLEXES; SPONTANEOUS RESOLUTION; HYDROGEN STORAGE; FRAMEWORK; LIGANDS; NETWORKS; BEHAVIOR; ACID;

D O I：

10.5560/ZNB.2013-2238

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A metal-organic framework based on 4-methylphthalic acid (H2L) and 4,4'-bipyridine (bpy), namely {[Cd(L)(bpy)(1.5)]center dot 2(H2O)}(n) (1), has been synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, thermogravimetry, and single-crystal X-ray crystallography. Complex 1 exhibits a 3D coordination network based on layers. Each layer consists of left- or right-handed {Cd-L-Cd-bpy-Cd-L-Cd-bpy}(n) double helices. Water molecules are also incorporated in the network. Compound 1 shows fluorescence at ca. 360 nm upon excitation at 304 nm.

引用

页码：127 / 132

页数：6

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