Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-Organic Cd(II) Coordination Polymer Based on Helical Units

被引：0
作者：
Li, Hai-Hua [1 ]
Zhang, Peng [1 ]
Pu, Jia-Yi [1 ]
Zhao, Yu-Ying [1 ]
Mei, Chong-Zhen [1 ]
机构：
[1] North China Univ Water Conservancy & Elect Power, Inst Environm & Municipal Engn, Zhengzhou 450011, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2013年 / 68卷 / 02期
关键词：
4-Methylphthalic Acid; Cd(II) Coordination Polymer; Double-helical Chain; Fluorescence; SUPRAMOLECULAR COMPLEXES; SPONTANEOUS RESOLUTION; HYDROGEN STORAGE; FRAMEWORK; LIGANDS; NETWORKS; BEHAVIOR; ACID;
D O I：
10.5560/ZNB.2013-2238
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A metal-organic framework based on 4-methylphthalic acid (H2L) and 4,4'-bipyridine (bpy), namely {[Cd(L)(bpy)(1.5)]center dot 2(H2O)}(n) (1), has been synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, thermogravimetry, and single-crystal X-ray crystallography. Complex 1 exhibits a 3D coordination network based on layers. Each layer consists of left- or right-handed {Cd-L-Cd-bpy-Cd-L-Cd-bpy}(n) double helices. Water molecules are also incorporated in the network. Compound 1 shows fluorescence at ca. 360 nm upon excitation at 304 nm.
引用
收藏
页码：127 / 132
页数：6
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