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Multistep mechanism for "hydride" transfer in the redox reactions induced by NAD(P)H- and NAD(P)+-models
被引:0
|作者:
Yasui, S
[1
]
Okamura, M
Fujii, M
机构:
[1] Tezukayama Coll, Nara 6318585, Japan
[2] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502102, Japan
[3] Kinki Univ, Dept Chem Engn, Iizuka, Fukuoka 8208555, Japan
来源:
关键词:
multistep mechanism;
NAD(P)H model;
redox;
D O I:
暂无
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The mechanistic studies presented to date concerning reductions by NAD(P)H models as well as oxidations by NAD(P)(+) models are outlined. Particularly emphasized are studies about how a net "hydride" is transferred from an NAD(P)H model to a substrate. A multistep mechanism including the initial electron transfer is shown to be more likely than a single-step mechanism.
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页码:145 / 165
页数:21
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