Camphor leaves extract as a neoteric and environment friendly inhibitor for Q235 steel in HCl medium: Combining experimental and theoretical researches

被引:52
|
作者
Chen, Shujun [1 ]
Zhao, Huajun [1 ]
Chen, Siyi [1 ]
Wen, Pushan [1 ]
Wang, Hao [1 ]
Li, Wenpo [2 ]
机构
[1] Zunyi Normal Univ, Coll Chem & Chem Engn, Zunyi 563002, Guizhou, Peoples R China
[2] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China
基金
美国国家科学基金会;
关键词
Camphor leaves extract; Q235; steel; AFM; SEM; Corrosion inhibitor; Langmuir adsorption; GREEN CORROSION-INHIBITOR; MILD-STEEL; COPPER CORROSION; MOLECULAR-DYNAMICS; SULFURIC-ACID; CU CORROSION; CARBON-STEEL; MECHANISM; DERIVATIVES; INSIGHTS;
D O I
10.1016/j.molliq.2020.113433
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Camphor leaves extract (CLE) as a neoteric and environment friendly inhibitor for Q235 steel in Ha medium was researched via experimental and theoretical researches. In this work, we used green, convenient pure water extraction method to obtain camphor leaves extract. Fourier transform infrared spectroscopy data show that there are many organic molecules with oxygen-containing functional groups in the organic in CLE. Electrochemical experimental data show that CLE is a mixed-type corrosion inhibitor and can exhibit good anti-corrosion performance. The concentration of CLE is 600 mg/L, its corrosion inhibition efficiency is 89.4% at 298 K. Surface morphology analysis (AFM and SEM) vividly shows the corrosion inhibition performance of CLE. The adsorption behavior of CLE onto Q235 steel/solution interface is obey Langmuir single-layer adsorption. Theoretical calculations show that CLE can exhibit good anti-corrosion performance. (C) 2020 Elsevier B.V. All rights reserved.
引用
收藏
页数:11
相关论文
共 50 条
  • [41] Expired flunarizine hydrochloride as corrosion inhibitors for Q235 steel in hydrochloric acid medium: Experimental and computational investigation
    Lin, Qiangwen
    Zhang, Qiao
    Huang, Yongbiao
    Luo, Yuzhou
    Zhang, Renhui
    Guo, Lei
    SURFACE AND INTERFACE ANALYSIS, 2023, 55 (10) : 774 - 786
  • [42] MPEC-IMI as an effective green inhibitor to protect Q235 steel in 0.5 M HCl medium
    Li Song
    Yuming Zhou
    Xiaoli Sheng
    Qingzhao Yao
    Xiaoyong Xi
    Research on Chemical Intermediates, 2018, 44 : 5833 - 5855
  • [43] Experimental and theoretical studies of Inula viscosa extract as a novel eco-friendly corrosion inhibitor for carbon steel in 1 M HCl
    Kouache, Amel
    Khelifa, Abdellah
    Boutoumi, Hocine
    Moulay, Saad
    Feghoul, Amira
    Idir, Brahim
    Aoudj, Salaheddine
    JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 2022, 36 (09) : 988 - 1016
  • [44] Dispersive adsorption and anticorrosion properties of natural capsaicin on Q235 steel in mixed H2SO4 and NaCl environment: Characterization, experimental and theoretical studies
    Emori, Wilfred
    Louis, Hitler
    Okonkwo, Paul C.
    Njoku, Demian I.
    Edet, Henry O.
    Okafor, Peter C.
    Cheng, Chun-Ru
    SUSTAINABLE CHEMISTRY AND PHARMACY, 2023, 32
  • [45] Preparation of Isoetes sinensis Extract as a Green Corrosion Inhibitor for Q235 Carbon Steel in Hydrochloric Acid
    Wang, Na
    Liu, Xiangxiang
    Jiang, Dewu
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2022, 17 (12):
  • [46] Inhibitory Effect of Pinus massoniana Needle Extract on Corrosion of Q235 Steel in Hydrochloric Acid Medium
    Wang, Xia
    Ren, Shuai-fei
    Zhang, Dai-xiong
    Jiang, Huan
    Gu, Yue
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2018, 13 (10): : 9888 - 9904
  • [47] Corrosion inhibition performance of Punica granatum L extract on Q235 steel in H2SO4 environment: Electrochemical, morphological, and quantum chemical studies
    Zhang, Jinliang
    Zhan, Fang
    Ai-Zaqri, Nobli
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2023, 18 (10):
  • [48] Experimental and theoretical investigation of inhibition behavior of bisflavanol for Q235 steel in hydrochloric acid solution
    Wang, Dan-Yang
    Nie, Bo-Li
    Li, Hui-Jing
    Wang, Fei
    Zhang, Wen-Zhuo
    Wu, Yan-Chao
    JOURNAL OF MOLECULAR LIQUIDS, 2021, 342
  • [49] Insights into the corrosion resistance of a novel quinoline derivative on Q235 steel in acidizing medium under hydrodynamic condition: experimental and surface study
    Singh, Ambrish
    Ansari, Kashif R.
    Ali, Ismat H.
    Younas, Muhammad
    Alanazi, Abdullah K.
    Lin, Yuanhua
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2024, 238 (08): : 1451 - 1473
  • [50] Experimental and Computational Study of Trachyspermum Leaves Extract as a Green Inhibitor for Corrosion Inhibition of Mild Steel in HCl
    Niloofar, Jafari
    Ali, Ahmadi Sayed
    Razieh, Razavi
    IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2023, 42 (10): : 3324 - 3337