Self-healing response in supramolecular polymers based on reversible zinc-histidine interactions

被引：64
|
作者：
Enke, Marcel [1 ,2 ]
Bode, Stefan [1 ,2 ]
Vitz, Juergen [1 ,2 ]
Schacher, Felix H. [1 ,2 ]
Harrington, Matthew J. [3 ]
Hager, Martin D. [1 ,2 ]
Schubert, Ulrich S. [1 ,2 ]
机构：
[1] Univ Jena, Lab Organ & Macromol Chem IOMC, D-07743 Jena, Germany
[2] Univ Jena, JCSM, D-07743 Jena, Germany
[3] Max Planck Inst Colloids & Interfaces, Dept Biomat, D-14424 Potsdam, Germany
来源：
POLYMER | 2015年 / 69卷
关键词：
Self-healing polymers; Bio-inspired materials; Metallopolymers; LIVING RADICAL POLYMERIZATION; MECHANICAL-PROPERTIES; RAFT PROCESS; VIBRATIONAL SPECTROSCOPY; ELASTIC-MODULUS; CROSS-LINKING; MUSSEL BYSSUS; AMINO-ACIDS; INDENTATION; COMPLEXES;
D O I：
10.1016/j.polymer.2015.03.068
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Histidine-metal interactions are utilized in many biological materials as reinforcing crosslinks, and in particular, are believed to contribute as reversible crosslinks to the intrinsic self-recovery behavior of mussel byssal threads. In this contribution, two new histidine-based monomers were synthesized and further copolymerized with butyl methacrylate (BMA) and lauryl methacrylate (LMA) applying the reversible addition-fragmentation chain transfer (RAFT) polymerization technique. Crosslinking with zinc ions resulted in supramolecular metallopolymer networks exhibiting a self-healing behavior that was tunable depending on the specific zinc salt used. The presented results provide a class of new polymeric species with different self-healing capacities. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：274 / 282
页数：9
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