Photonic crystals with SiO2-Ag "post-cap" nanostructure coatings for surface enhanced Raman spectroscopy

We demonstrate that the resonant near fields of a large-area replica molded photonic crystal (PC) slab can efficiently couple light from a laser to SiO2-Ag "post-cap" nanostructures deposited on the PC surface by a glancing angle evaporation technique for achieving high surface enhanced Raman spectroscopy (SERS) enhancement factor. To examine the feasibility of the PC-SERS substrate, the simulated electric field around individual Ag particles and the measured Raman spectrum of trans-1,2-bis(4pyridyl)ethane on the PC-SERS substrate were compared with those from an ordinary glass substrate coated with the same SiO2-Ag nanostructures. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2998695]