Infrared Quantum Dots: Progress, Challenges, and Opportunities

被引:310
作者
Lu, Haipeng [1 ]
Carroll, Gerard M. [1 ]
Neale, Nathan R. [1 ]
Beard, Matthew C. [1 ]
机构
[1] Natl Renewable Energy Lab, Chem & Nanosci Ctr, Golden, CO 80401 USA
关键词
LIGHT-EMITTING-DIODES; MULTIPLE EXCITON GENERATION; METAL CHALCOGENIDE NANOCRYSTALS; NONTHERMAL PLASMA SYNTHESIS; COLLOIDAL PBS NANOCRYSTALS; SOLAR-CELLS; SILICON NANOCRYSTALS; BAND-GAP; CARRIER MULTIPLICATION; IN-SITU;
D O I
10.1021/acsnano.8b09815
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Infrared technologies provide tremendous value to our modern-day society. The need for easy-to-fabricate, solution-processable, tunable infrared active optoelectronic materials has driven the development of infrared colloidal quantum dots, whose band gaps can readily be tuned by dimensional constraints due to the quantum confinement effect. In this Perspective, we summarize recent progress in the development of infrared quantum dots both as infrared light emitters (e.g., in light-emitting diodes, biological imaging, etc.) as well as infrared absorbers (e.g., in photovoltaics, solar fuels, photon up-conversion, etc.), focusing on how fundamental breakthroughs in synthesis, surface chemistry, and characterization techniques are facilitating the implementation of these nanostructures into exploratory device architectures as well as in emerging applications. We discuss the ongoing challenges and opportunities associated with infrared colloidal quantum dots.
引用
收藏
页码:939 / 953
页数:15
相关论文
共 152 条
[51]   A tunable library of substituted thiourea precursors to metal sulfide nanocrystals [J].
Hendricks, Mark P. ;
Campos, Michael P. ;
Cleveland, Gregory T. ;
Jen-La Plante, Ilan ;
Owen, Jonathan S. .
SCIENCE, 2015, 348 (6240) :1226-1230
[52]   A Solution NMR Toolbox for Characterizing the Surface Chemistry of Colloidal Nanocrystals [J].
Hens, Zeger ;
Martins, Jose C. .
CHEMISTRY OF MATERIALS, 2013, 25 (08) :1211-1221
[53]   Size and Shape Control of Colloidally Synthesized IV-VI Nanoparticulate Tin(II) Sulfide [J].
Hickey, Stephen G. ;
Waurisch, Christian ;
Rellinghaus, Bernd ;
Eychmueller, Alexander .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (45) :14978-+
[54]   Colloidal PbS nanocrystals with size-tunable near-infrared emission: Observation of post-synthesis self-narrowing of the particle size distribution [J].
Hines, MA ;
Scholes, GD .
ADVANCED MATERIALS, 2003, 15 (21) :1844-1849
[55]   Semiconductor Nanocrystal Light Absorbers for Photon Upconversion [J].
Huang, Zhiyuan ;
Tang, Ming Lee .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (21) :6198-6206
[56]   Hybrid Molecule-Nanocrystal Photon Upconversion Across the Visible and Near-Infrared [J].
Huang, Zhiyuan ;
Li, Xin ;
Mahboub, Melika ;
Hanson, Kerry M. ;
Nichols, Valerie M. ;
Le, Hoang ;
Tang, Ming L. ;
Bardeen, Christopher J. .
NANO LETTERS, 2015, 15 (08) :5552-5557
[57]   Nonthermal Plasma Synthesis of Core/Shell Quantum Dots: Strained Ge/Si Nanocrystals [J].
Hunter, Katharine I. ;
Held, Jacob T. ;
Mkhoyan, K. Andre ;
Kortshagen, Uwe R. .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (09) :8263-8270
[58]   Synthesis and Optical Properties of Lead-Free Cesium Tin Halide Perovskite Nanocrystals [J].
Jellicoe, Tom C. ;
Richter, Johannes M. ;
Glass, Hugh F. J. ;
Tabachnyk, Maxim ;
Brady, Ryan ;
Dutton, Sian E. ;
Rao, Akshay ;
Friend, Richard H. ;
Credgington, Dan ;
Greenham, Neil C. ;
Boehm, Marcus L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (09) :2941-2944
[59]   SiC formation for a solar cell passivation layer using an RF magnetron co-sputtering system [J].
Joung, Yeun-Ho ;
Kang, Hyun Il ;
Kim, Jung Hyun ;
Lee, Hae-Seok ;
Lee, Jaehyung ;
Choi, Won Seok .
NANOSCALE RESEARCH LETTERS, 2012, 7
[60]   Silicon nanocrystals with ensemble quantum yields exceeding 60% [J].
Jurbergs, David ;
Rogojina, Elena ;
Mangolini, Lorenzo ;
Kortshagen, Uwe .
APPLIED PHYSICS LETTERS, 2006, 88 (23)