Furazan-containing bromoarenes in the Suzuki-Miyaura reaction

被引:8
|
作者
Vasil'ev, A. A. [1 ]
Struchkova, M. I. [1 ]
Sheremetev, A. B. [1 ]
Levinson, F. S. [2 ]
Varganov, R. V. [2 ]
Lyssenko, K. A. [3 ]
机构
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia
[2] Kazan State Technol Univ, Kazan 420015, Russia
[3] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
关键词
furazans; benzofurazans; bromoarenes; arylboronic acids; cross-coupling; Suzuki-Miyaura reaction; CROSS-COUPLING REACTIONS; ACTIVE PALLADIUM CATALYSTS; ARYLBORONIC ACIDS; COMPLEXES; TEMPERATURE; DERIVATIVES; DENSITIES; LIGANDS; BIARYLS; HALIDES;
D O I
10.1007/s11172-011-0353-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The palladium-catalyzed cross-coupling reactions of 3-[bromo(het)aryl]furazans and bromobenzofurazans with arylboronic acids afford target biaryls in good yields. 3-Bromo-4-phenylfurazan containing a bromine atom in the furazan ring undergoes decomposition under the reaction conditions.
引用
收藏
页码:2306 / 2314
页数:9
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