Synthesis, characterization, and applications of group 13 cationic compounds

被引：140
作者：
Dagorne, Samuel [1 ]
Atwood, David A.
机构：
[1] Univ Strasbourg, Inst Chim, F-67000 Strasbourg, France
来源：
CHEMICAL REVIEWS | 2008年 / 108卷 / 10期
关键词：
D O I：
10.1021/cr078351k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Six-coordinate aluminum cations (and related neutral derivatives) supported by Salen and porphyrin ligands have now become widely used for catalytic applications including propylene oxide polymerization and a wide range of carbonylation reactions. These applications rely on the stable environment provided by the ligands and the Lewis acidity of the cations. In the carbonylation reactions, added Lewis basic ligands are needed to mitigate the cationic charge on the aluminum atom. © 2008 American Chemical Society.
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页码：4037 / 4071
页数：35
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