A New Biscarbazole-Based Metal-Organic Framework for Efficient Host-Guest Energy Transfer

被引：21

作者：

Mu, Qianqian ^{[1
,2
]}

Liu, Jingjuan ^{[1
,2
]}

Chen, Weiben ^{[1
,2
]}

Song, Xiaoyu ^{[1
,2
]}

Liu, Xiaoting ^{[3
]}

Zhang, Xiaotao ^{[1
,2
]}

Chang, Ze ^{[3
]}

Chen, Long ^{[1
,2
]}

机构：

[1] Tianjin Univ, Dept Chem, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300072, Peoples R China

[2] Tianjin Univ, Inst Mol Plus, Tianjin 300072, Peoples R China

[3] Nankai Univ, Sch Mat Sci & Engn, Natl Inst Adv Mat, TKL Met & Mol Based Mat Chem, Tianjin 300350, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2019年 / 25卷 / 08期

基金：

中国国家自然科学基金;

关键词：

energy transfer; fluorescence; host-guest systems; in situ encapsulation; metal-organic frameworks; ADSORPTION; MOF; FLUORESCENCE; SEPARATION; LINKERS; SENSOR;

D O I：

10.1002/chem.201805636

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new metal-organic framework (MOF), [Zn6L4(Me2NH2+)(4)3H(2)O] (1) was constructed based on [9, 9-biscarbazole]-3, 3, 6, 6-tetracarboxylic acid (H4L) and Zn2+ ions. The porous framework and intense blue fluorescence of the MOF based on the biscarbazole moiety of the ligand could facilitate efficient host to guest energy transfer, which makes it an ideal platform for the tuning of luminescence.

引用

页码：1901 / 1905

页数：5

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