Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide-imine complexes

被引：33
|
作者：
Takaki, K [1 ]
Sonoda, K [1 ]
Kousaka, T [1 ]
Koshoji, G [1 ]
Shishido, T [1 ]
Takehira, K [1 ]
机构：
[1] Hiroshima Univ, Grad Sch Engn, Dept Chem & Chem Engn, Higashihiroshima 7398527, Japan
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 52期
关键词：
hydrosilylation; double silylation; lanthanide catalyst; olefins; conjugated dienes;
D O I：
10.1016/S0040-4039(01)02027-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl- and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, Under similar conditions. (C) 2001 Elsevier Science Ltd. ALI rights reserved.
引用
收藏
页码：9211 / 9214
页数：4
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