MILD AND EFFICIENT CHEMOSELECTIVE TETRAHYDROPYRANYLATION OF ALCOHOLS USING BRONSTED ACIDIC IONIC LIQUID AS CATALYST UNDER SOLVENT-FREE CONDITIONS

被引:12
|
作者
Hajipour, Abdol R. [1 ,2 ]
Nasresfahani, Zahra [1 ]
机构
[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran
[2] Univ Wisconsin, Dept Pharmacol, Sch Med, Madison, WI 53706 USA
关键词
Alcohols; Bronsted acidic; ionic liquid; OTHP; protection; CARBONYL-COMPOUNDS; SOLID-PHASE; SELECTIVE TETRAHYDROPYRANYLATION; AROMATIC-COMPOUNDS; ALUMINUM-CHLORIDE; OXIDATION; REAGENT; SILICA; PHENOLS; IODINATION;
D O I
10.1080/00397911.2010.551286
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A straightforward and efficient method for preparation of morpholinium bisulfate ([mroH]HSO4) as a novel acidic ionic liquid is reported. The application of this efficient and inexpensive acidic ionic liquid catalyst for tetrahydropyranylation of alcohols under mild and solvent-free conditions at room was investigated.
引用
收藏
页码:1995 / 2006
页数:12
相关论文
共 50 条
  • [31] Mild preparation of chromeno[2,3-d]pyrimidines catalyzed by Bronsted acidic ionic liquids under solvent-free and ambient conditions
    Shaterian, Hamid Reza
    Aghakhanizadeh, Morteza
    RESEARCH ON CHEMICAL INTERMEDIATES, 2013, 39 (08) : 3877 - 3885
  • [32] Fast selective oxidation of alcohols under solvent-free conditions
    Saffar-Teluri, Ali
    RESEARCH ON CHEMICAL INTERMEDIATES, 2013, 39 (07) : 3337 - 3343
  • [33] Silica sulfuric acid as an efficient and recyclable catalyst for the methoxymethylation of alcohols under solvent-free conditions
    Niknam, Khodabakhsh
    Zolfigol, Mohammad Ali
    Khorramabadi-Zad, Ahmad
    Zare, Reza
    Shayegh, Mohsen
    CATALYSIS COMMUNICATIONS, 2006, 7 (07) : 494 - 498
  • [34] A Bronsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols
    Zhang, Lei
    Xian, Mo
    He, Yucai
    Li, Liangzhi
    Yang, Jianming
    Yu, Shitao
    Xu, Xin
    BIORESOURCE TECHNOLOGY, 2009, 100 (19) : 4368 - 4373
  • [35] Mild and efficient solvent-free tetrahydropyranylation (THP) of alcohols catalyzed by reusable acidic ionic liquid [Et3N(CH2)(4)SO3H][OTs]
    Hajipour, Abdol Reza
    Azizi, Ghobad
    IRANIAN JOURNAL OF CATALYSIS, 2014, 4 (03): : 213 - 218
  • [36] Ionic liquid catalyzed solvent-free synthesis of chalcone and its derivatives under mild conditions
    Zhao, Qiu
    Wang, Gang
    Liao, Fuxia
    Sha, Yifan
    Xu, Fei
    Li, Chunshan
    Li, Zengxi
    Cao, Yijun
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2021, 33 : 160 - 166
  • [37] An Efficient Bifunctional Ionic Liquid [BIL] as Solvent and Catalyst System for O-Alkylation of Phenols Under Solvent-Free Conditions: An Environmental Benign Approach
    Jayaraman, Sakthinarayanan
    Selvarasu, Uthayanila
    Selvaraj, Ganesh Gopalsamy
    Parasuraman, Karthikeyan
    LETTERS IN ORGANIC CHEMISTRY, 2022, 19 (07) : 570 - 575
  • [38] Mild and efficient silylation of alcohols under ambient and solvent-free conditions with phosphorus pentoxide supported on alumina (P2O5/Al2O3) as catalyst
    Shaterian, Hamid Reza
    Fahimi, Nafiseh
    Azizi, Kobra
    RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (02) : 947 - 954
  • [39] A Facile and Efficient Catalytic System for the Oxidation of Alcohols with Gold(III) and Ionic Liquid Immobilized TEMPO under Solvent-Free Conditions
    Wang, Zhao-gang
    Xu, Kui
    Shen, Meng-nan
    Lu, Ming
    SYNLETT, 2014, 25 (17) : 2459 - 2462
  • [40] Bismuth oxide perchlorate as a highly efficient and chemoselective catalyst for thioacetalization of carbonyl compounds under solvent-free conditions
    Kumar, BS
    Reddy, YT
    Reddy, PN
    Rao, GVP
    Rajitha, B
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2005, 44 (11): : 2387 - 2389