MILD AND EFFICIENT CHEMOSELECTIVE TETRAHYDROPYRANYLATION OF ALCOHOLS USING BRONSTED ACIDIC IONIC LIQUID AS CATALYST UNDER SOLVENT-FREE CONDITIONS

被引：12
|
作者：
Hajipour, Abdol R. [1 ,2 ]
Nasresfahani, Zahra [1 ]
机构：
[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran
[2] Univ Wisconsin, Dept Pharmacol, Sch Med, Madison, WI 53706 USA
来源：
SYNTHETIC COMMUNICATIONS | 2012年 / 42卷 / 13期
关键词：
Alcohols; Bronsted acidic; ionic liquid; OTHP; protection; CARBONYL-COMPOUNDS; SOLID-PHASE; SELECTIVE TETRAHYDROPYRANYLATION; AROMATIC-COMPOUNDS; ALUMINUM-CHLORIDE; OXIDATION; REAGENT; SILICA; PHENOLS; IODINATION;
D O I：
10.1080/00397911.2010.551286
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A straightforward and efficient method for preparation of morpholinium bisulfate ([mroH]HSO4) as a novel acidic ionic liquid is reported. The application of this efficient and inexpensive acidic ionic liquid catalyst for tetrahydropyranylation of alcohols under mild and solvent-free conditions at room was investigated.
引用
收藏
页码：1995 / 2006
页数：12
相关论文
共 50 条
  • [1] Tetrahydropyranylation of Alcohols Under Solvent-Free Conditions
    Hajipour, Abdol R.
    Kargosha, Majid
    Ruoho, Arnold E.
    SYNTHETIC COMMUNICATIONS, 2009, 39 (06) : 1084 - 1091
  • [2] Bronsted acidic ionic liquids: Fast, mild, and efficient catalysts for solvent-free tetrahydropyranylation of alcohols
    Duan, ZY
    Gu, YL
    Deng, YQ
    SYNTHETIC COMMUNICATIONS, 2005, 35 (14) : 1939 - 1945
  • [3] 1,6-HEXANEDIAMINE METHANESULFONATE: A MILD AND EFFICIENT CATALYST FOR THE TETRAHYDROPYRANYLATION OF ALCOHOLS UNDER SOLVENT-FREE CONDITIONS
    Wang, Rui
    Jiang, Heng
    PREPARATIVE BIOCHEMISTRY & BIOTECHNOLOGY, 2010, 40 (03) : 171 - 176
  • [4] N-bromosuccinimide (NBS):: a mild and efficient catalyst for tetrahydropyranylation of alcohols and Phenols under solvent-free conditions
    Khazaei, Ardeshir
    Rostami, Amin
    Raiatzadeh, Ayeh
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2007, 54 (04) : 1029 - 1032
  • [5] An efficient Bronsted-Lewis acidic ionic liquid catalyzed tetrahydropyranylation of alcohols
    Azizi, Najmedin
    Abdoli-Senejani, Masumeh
    Abbasi, Faezeh
    TETRAHEDRON LETTERS, 2016, 57 (45) : 5009 - 5011
  • [6] Phosphorus pentoxide as an efficient catalyst for the tetrahydropyranylation of alcohols under solvent free conditions
    Eshghi, H
    Shafieyoon, P
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2004, 179 (10) : 2149 - 2152
  • [7] Ferrous methanesulfonate as an efficient and recyclable catalyst for the tetrahydropyranylation of alcohols and phenols under solvent-free conditions
    Wang, Min
    Song, Zhiguo
    Wan, Xin
    Zhao, Shuang
    RSC ADVANCES, 2011, 1 (09): : 1698 - 1700
  • [8] Al(OTf)3 - A highly efficient catalyst for the tetrahydropyranylation of alcohols under solvent-free conditions
    Kamal, Ahmed
    Khan, M. Naseer A.
    Srikanth, Y. V. V.
    Reddy, K. Srinivasa
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2008, 86 (12): : 1099 - 1104
  • [9] Ruthenium(III) acetylacetonate [Ru(acac)3] -: An efficient chemoselective catalyst for the tetrahydropyranylation (THP) of alcohols and phenols under solvent-free conditions
    Varala, Ravi
    Adapa, Srinivas R.
    CANADIAN JOURNAL OF CHEMISTRY, 2006, 84 (09) : 1174 - 1179
  • [10] Pyridinium p-Toluenesulfonate: A Mild and Efficient Catalyst for The Regioselective Tetrahydropyranylation of Indazole Derivatives Under Solvent-Free Conditions
    Thatipally, Suresh
    Acharyulu, Palle V. R.
    Dubey, P. K.
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (01) : 451 - 454
12345