Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate)

被引：41

作者：

Celik, Murat ^{[1
]}

Alp, Cemalettin

Coskun, Betul

Gultekin, M. Serdar

Balci, Metin

机构：

[1] Ataturk Univ, Dept Chem, TR-25240 Erzurum, Turkey

[2] Middle E Tech Univ, Dept Chem, TR-06530 Ankara, Turkey

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 22期

关键词：

phenyliodine(III) bis(trifluoroacetate); PIFA; oxidation; rearrangement; 1.2-diols; 1.3-diols;

D O I：

10.1016/j.tetlet.2006.03.137

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1.2- and 1.3-Bis(trifluoroacetoxy) alcohols are easily obtained from the one-pot reaction of alkenes with phenyliodine(III) bis(trifluoroacetate) (PIFA) in the absence of any additive or catalyst. The products were converted into the corresponding diols by ammonolysis. The use of bicyclic alkenes has shown that rearranged 1,3-diacetoxy alcohols are mostly formed as the major products. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：3659 / 3663

页数：5

共 39 条

[1]

Backvall J.-E., 2010, Modern Oxidation Methods, V2nd

[2] PALLADIUM-HYDROQUINONE CATALYZED ELECTROCHEMICAL 1,4-OXIDATION OF CONJUGATED DIENES [J].