Efficient transition-metal-free oxidation of benzylic and secondary alcohols to the carbonyl compounds using an N-bromosuccinimide/NH4Cl system

被引：10
|
作者：
Jain, SL [1 ]
Sain, B [1 ]
机构：
[1] Indian Inst Petr, Chem & Biotechnol Div, Dehra Dun 248005, Uttar Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2006年 / 36卷 / 10期
关键词：
oxidation; alcohol; NBS; metal free; ketone;
D O I：
10.1080/00397910500522207
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The oxidation of a variety of benzylic and secondary alcohols was achieved in excellent yields using an NBS/NH4Cl system in aqueous acetonitrile (CH3CN-H2O; 7/3v/v) at 80 degrees C under very mild conditions.
引用
收藏
页码：1459 / 1462
页数：4
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