Flexible clay hybrid films with various poly(vinyl alcohol) contents: Thermal properties, morphology, optical transparency, and gas permeability

被引:2
|
作者
Shin, Jieun [1 ]
Kim, Jeong-Cheol [2 ]
Chang, Jin-Hae [3 ]
机构
[1] Kumoh Natl Inst Technol, Ctr Sci Instruments, Gyeongbuk 730701, South Korea
[2] Korea Inst Ind Technol, Energy & Appl Opt Team, Kwangju 500480, South Korea
[3] Kumoh Natl Inst Technol, Sch Energy & Integrated Mat Engn, Gyeongbuk 730701, South Korea
关键词
saponite; poly(vinyl alcohol) (PVA); hybrid; flexible film; LAYERED-SILICATE NANOCOMPOSITES; BARRIER PROPERTIES; PERMEATION PROPERTIES; POLYIMIDE FILMS; POLYMER; COMPOSITE; MONTMORILLONITE; FLAMMABILITY; COLORLESS;
D O I
10.1007/s13233-013-1182-7
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Clay hybrid films were obtained by the solution blending of saponite (SPT) with various amounts of poly(vinyl alcohol) (PVA). Variations in the thermal properties, morphology, optical transparency, and gas permeability of the clay hybrid films with PVA content in the range 0-10 wt% were examined. With increasing PVA content, the thermal transition temperatures of the hybrids decreased. However, the values of the coefficient of thermal expansion (CTE) increased gradually. The values of the yellow index (YI) and oxygen transmission rate (O2TR) of the clay hybrid films remained constant regardless of their PVA content.
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页码:1349 / 1354
页数:6
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