2,6-Dihalo-9-selenabicyclo[3.3.1]nonanes and their complexes with selenium dihalides: synthesis and structural characterisation

被引：36

作者：

Potapov, Vladimir A. ^{[1
]}

Amosova, Svetlana V. ^{[1
]}

Abramova, Elena V. ^{[1
]}

Musalov, Maxim V. ^{[1
]}

Lyssenko, Konstantin A. ^{[2
]}

Finn, M. G. ^{[3
]}

机构：

[1] Russian Acad Sci, Siberian Div, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 117813, Russia

[3] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 10期

基金：

俄罗斯科学基金会;

关键词：

SPECTROSCOPIC CHARACTERIZATION; STEREOSELECTIVE-SYNTHESIS; MOLECULAR-STRUCTURE; SULFUR DICHLORIDE; DIBROMIDE; COORDINATION; ANNULATION; CHEMISTRY; SULFIDES; CRYSTAL;

D O I：

10.1039/c5nj00684h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transannular addition of SeCl2 and SeBr2 to cis,cis-cycloocta-1,5-diene affords 2,6-dihalo-9-selenabicyclo[3.3.1]nonanes in high yields. The latter react with SeCl2 and SeBr2 to form the 2:1 complexes, which are the first representatives of coordination compounds with the Se center dot center dot center dot Se center dot center dot center dot Se bonds. X-ray crystallographic data of the obtained compounds are discussed. In contrast to 2,6-dihalo-9-selenabicyclo[3.3.1]nonanes, tetrahydroselenophene does not form complexes with SeCl2 and SeBr2 giving 1,1-dihalotetrahydroselenophenes.

引用

页码：8055 / 8059

页数：5

共 22 条

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[22] Synthesis, characterisation and X-ray studies of mixed-ligand triruthenium cluster complexes, Ru3(CO)9(arphos)(L), where L = PCy3, PPh3, P(C6H4F-m)3, P(C6H4F-p)3, P(C6H4Cl-p)3 and PPh(C6H4OMe-p)2
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