2,6-Dihalo-9-selenabicyclo[3.3.1]nonanes and their complexes with selenium dihalides: synthesis and structural characterisation

被引：36
|
作者：
Potapov, Vladimir A. [1 ]
Amosova, Svetlana V. [1 ]
Abramova, Elena V. [1 ]
Musalov, Maxim V. [1 ]
Lyssenko, Konstantin A. [2 ]
Finn, M. G. [3 ]
机构：
[1] Russian Acad Sci, Siberian Div, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia
[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 117813, Russia
[3] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
来源：
NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 10期
基金：
俄罗斯科学基金会;
关键词：
SPECTROSCOPIC CHARACTERIZATION; STEREOSELECTIVE-SYNTHESIS; MOLECULAR-STRUCTURE; SULFUR DICHLORIDE; DIBROMIDE; COORDINATION; ANNULATION; CHEMISTRY; SULFIDES; CRYSTAL;
D O I：
10.1039/c5nj00684h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The transannular addition of SeCl2 and SeBr2 to cis,cis-cycloocta-1,5-diene affords 2,6-dihalo-9-selenabicyclo[3.3.1]nonanes in high yields. The latter react with SeCl2 and SeBr2 to form the 2:1 complexes, which are the first representatives of coordination compounds with the Se center dot center dot center dot Se center dot center dot center dot Se bonds. X-ray crystallographic data of the obtained compounds are discussed. In contrast to 2,6-dihalo-9-selenabicyclo[3.3.1]nonanes, tetrahydroselenophene does not form complexes with SeCl2 and SeBr2 giving 1,1-dihalotetrahydroselenophenes.
引用
收藏
页码：8055 / 8059
页数：5
相关论文
共 22 条
  • [1] Efficient Synthesis of a New Family of 2,6-Disulfanyl-9-selenabicyclo[3.3.1]nonanes
    Musalov, Maxim, V
    Potapov, Vladimir A.
    Amosova, Svetlana, V
    MOLECULES, 2021, 26 (10):
  • [2] Synthesis and characterisation of complexes of the 2,6-diphenoxyphenyl ligand
    Blake, Alexander J.
    Gower, Alexandra L.
    Lewis, William
    Moxey, Graeme J.
    Reade, Thomas J.
    Kays, Deborah L.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (09) : 1787 - 1791
  • [3] A STUDY ON THE AMINOMERCURATION-NUCLEOPHILIC DEMERCURATION OF CIS-CIS-1,5-CYCLOOCTADIENE - STEREOSELECTIVE SYNTHESIS OF 2,6-DISUBSTITUTED-9-AZA BICYCLO[3.3.1]NONANES
    BARLUENGA, J
    PEREZPRIETO, J
    ASENSIO, G
    GARCIAGRANDA, S
    SALVADO, MA
    TETRAHEDRON, 1992, 48 (18) : 3813 - 3826
  • [4] Reactions of selenium dichloride and dibromide with divinyl selenide: synthesis of novel selenium heterocycles and rearrangement of 2,6-dihalo-1,4-diselenanes
    Potapov, Vladimir A.
    Amosova, Svetlana V.
    Volkova, Kaleria A.
    Penzik, Maxim V.
    Albanov, Alexander I.
    TETRAHEDRON LETTERS, 2010, 51 (01) : 89 - 92
  • [5] Lanthanide complexes with N-(2,6-dimethylphenyl)oxamate: Synthesis, characterisation and cytotoxicity
    Madanhire, Tatenda
    Davids, Hajierah
    Pereira, Melanie C.
    Hosten, Eric C.
    Abrahams, Abubak'r
    POLYHEDRON, 2020, 184
  • [6] Intramolecular Hydrogen Bonding in CuII Complexes with 2,6-Pyridinedicarboxamide Ligands: Synthesis, Structural Characterization, and Physical Properties
    Wang, Denan
    Lindeman, Sergey V.
    Fiedler, Adam T.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (25) : 4473 - 4484
  • [7] Synthesis, structural and magnetic characterizations of new complexes of di-2,6-(2-pyridylcarbonyl)pyridine (pyCOpyCOpy) ligand
    Calancea, Sergiu
    Pinero, Dalice
    Poirot, David
    Mathoniere, Corine
    Rosa, Patrick
    Clerac, Rodolphe
    Pejo, Carolina
    Chiozzone, Raul
    Lloret, Francesc
    Gonzalez, Ricardo
    POLYHEDRON, 2013, 64 : 294 - 303
  • [8] PtII-catalyzed synthesis of 9-oxabicyclo-[3.3.1]nona-2,6-dienes from 2-alkynyl-1-carbonylbenzenes and allylsilanes by an allylation/annulation cascade
    Bhunia, Sabyasachi
    Wang, Kuo-Chang
    Liu, Rai-Shung
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (27) : 5063 - 5066
  • [9] A new 2,6-di(anthracen-9-yl)pyridine ligand and its complexes with Ag(I) ions: Synthesis, structure and photocatalytic activity
    Marcinkowski, Damian
    Walesa-Chorab, Monika
    Kubicki, Maciej
    Hoffmann, Marcin
    Kadziolka, Grzegorz
    Michalkiewicz, Beata
    Patroniak, Violetta
    POLYHEDRON, 2015, 90 : 91 - 98
  • [10] 3d Metal Complexes Supported by a Bis(imidazolin-2-imino)pyridine Pincer Ligand - Synthesis, Structural Characterisation, and Magnetic Properties
    Filimon, Sabina-Alexandra
    Petrovic, Dejan
    Volbeda, Jeroen
    Bannenberg, Thomas
    Jones, Peter G.
    von Richthofen, Carl-Georg Freiherr
    Glaser, Thorsten
    Tamm, Matthias
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (35) : 5997 - 6012
123