Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction

被引：2

作者：

Wang Ying ^{[1
]}

Wang Qiliao ^{[2
,3
]}

Hou Liman ^{[2
]}

Zhou Mingdong ^{[1
]}

Dong Dewen ^{[2
]}

Zhang Ning ^{[2
]}

机构：

[1] Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, CAS Key Lab High Performance Synthet Rubber & Its, Changchun 130022, Jilin, Peoples R China

[3] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2019年 / 35卷 / 02期

关键词：

Cyclic phosphonate; Ring-opening polymerization; Thiol-ene click reaction; Post modification; POLY(VINYLPHOSPHONIC ACID); PHOSPHATES); COPOLYMER; EFFICIENT; PROGRESS;

D O I：

10.1007/s40242-019-8309-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(ethylene phosphonate) was synthesized via the living ring-opening polymerization of cyclic phosphonate monomer catalyzed by organocatalyst. The pendant vinyl functionalities were employed to perform the photochemical click reactions with thiols. We demonstrated that both small thiol molecules and macromolecular thiols could be efficiently coupled into the PPE side chains, enabling the rapid and efficient functionalization of polyphosphoesters(PPE).

引用

页码：340 / 344

页数：5

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