Characterization and adsorptive properties of cross-linked poly (1-vinylimidazole)-iron (III) complex synthesized in supercritical carbon dioxide

In this study, poly (1-vinylimidazole)-iron(III) [PVIm-Fe(III)] complex was investigated along with adsorption behavior of bovine serum albumin (BSA). The cross-linked PVIm-Fe(III) was synthesized in supercritical carbon dioxide by using N, N'-methylenebisacrylamide (BIS) as a cross-linker. The obtained products were analyzed using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectra (XPS) analysis. The results reveal that iron ion is complexed by coordination with basic (-N) functional groups of 1-vinylimidazole successfully. The effects of the operating pressure, the ratio of iron and cross-linker concentration were investigated. A fine and yellow powder was obtained at high yield and crosslinking degrees at 20 MPa, 70 degrees C. Additionally, the property of PVIm-Fe(III) complexes in terms of BSA adsorption has been studied, and the higher adsorption capacity was 660 mg/g.