Simple Nickel-Based Catalyst Systems Combined With Graphitic Carbon Nitride for Stable Photocatalytic Hydrogen Production in Water

被引：128

作者：

Dong, Jingfeng ^{[1
]}

Wang, Mei ^{[1
]}

Li, Xueqiang ^{[1
]}

Chen, Lin ^{[1
]}

He, Yu ^{[1
]}

Sun, Licheng ^{[1
,2
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, DUT KTH Joint Educ & Res Ctr Mol Devices, Dalian 116012, Peoples R China

[2] Royal Inst Technol KTH, Dept Chem, S-10044 Stockholm, Sweden

来源：

CHEMSUSCHEM | 2012年 / 5卷 / 11期

关键词：

carbon nitrides; hydrogen production; nickel; photocatalysis; water splitting; ELECTRON-TRANSFER; REDUCTION; COMPLEXES; METALLOPORPHYRIN; COBALOXIMES; OXIDATION; CO;

D O I：

10.1002/cssc.201200490

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A molecular catalyst system containing only earth-abundant elements is combined with g-C3N4 as photosensitizer. The in situ generated complexes serve as catalysts for visible-light-driven H2 production in aqueous solution, and do not require organic solvent or a Brønsted acid. H2 evolution from the Ni-based catalyst system can be maintained for over 60 h, demonstrating that the combination is a promising approach to improve the lifetimes of molecular catalysts towards photochemical H2 production. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2133 / 2138

页数：6

共 48 条

[1] Boron-Capped Tris(glyoximato) Cobalt Clathrochelate as a Precursor for the Electrodeposition of Nanoparticles Catalyzing H2 Evolution in Water [J].

Anxolabehere-Mallart, Elodie ;

Costentin, Cyrille ;

Fournier, Maxime ;

Nowak, Sophie ;

Robert, Marc ;

Saveant, Jean-Michel .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (14) :6104-6107

[2]

Artero V., 2011, ANGEW CHEM, V123, P7376, DOI [DOI 10.1002/ANIE.201007987, DOI 10.1002/ange.201007987]

[3] Splitting Water with Cobalt [J].

Artero, Vincent ;

Chavarot-Kerlidou, Murielle ;

Fontecave, Marc .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) :7238-7266

[4] Solar Energy Supply and Storage for the Legacy and Non legacy Worlds [J].

Cook, Timothy R. ;

Dogutan, Dilek K. ;

Reece, Steven Y. ;

Surendranath, Yogesh ;

Teets, Thomas S. ;

Nocera, Daniel G. .

CHEMICAL REVIEWS, 2010, 110 (11) :6474-6502

[5] Kinetics of Electron Transfer Reactions of H2-Evolving Cobalt Diglyoxime Catalysts [J].

Dempsey, Jillian L. ;

Winkler, Jay R. ;

Gray, Harry B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) :1060-1065

[6] Promoting Effect of Electrostatic Interaction between a Cobalt Catalyst and a Xanthene Dye on Visible-Light-Driven Electron Transfer and Hydrogen Production [J].

Dong, Jingfeng ;

Wang, Mei ;

Zhang, Pan ;

Yang, Songqiu ;

Liu, Jianyong ;

Li, Xueqiang ;

Sun, Licheng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (30) :15089-15096

[7] Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges [J].

Du, Pingwu ;

Eisenberg, Richard .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (03) :6012-6021

[8]

Duortail G., 1977, BIOPOLYMERS, V16, P1397

[9] Discovery and high-throughput screening of heteroleptic iridium complexes for photoinduced hydrogen production [J].

Goldsmith, JI ;

Hudson, WR ;

Lowry, MS ;

Anderson, TH ;

Bernhard, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) :7502-7510

[10] Visible light induced photopolymerization: speeding up the rate of polymerization by using co-initiators in dye/amine photoinitiating systems [J].

Grotzinger, C ;

Burget, D ;

Jacques, P ;

Fouassier, JP .

POLYMER, 2003, 44 (13) :3671-3677

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