Simple Nickel-Based Catalyst Systems Combined With Graphitic Carbon Nitride for Stable Photocatalytic Hydrogen Production in Water

被引：128
作者：
Dong, Jingfeng [1 ]
Wang, Mei [1 ]
Li, Xueqiang [1 ]
Chen, Lin [1 ]
He, Yu [1 ]
Sun, Licheng [1 ,2 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, DUT KTH Joint Educ & Res Ctr Mol Devices, Dalian 116012, Peoples R China
[2] Royal Inst Technol KTH, Dept Chem, S-10044 Stockholm, Sweden
来源：
CHEMSUSCHEM | 2012年 / 5卷 / 11期
关键词：
carbon nitrides; hydrogen production; nickel; photocatalysis; water splitting; ELECTRON-TRANSFER; REDUCTION; COMPLEXES; METALLOPORPHYRIN; COBALOXIMES; OXIDATION; CO;
D O I：
10.1002/cssc.201200490
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A molecular catalyst system containing only earth-abundant elements is combined with g-C3N4 as photosensitizer. The in situ generated complexes serve as catalysts for visible-light-driven H2 production in aqueous solution, and do not require organic solvent or a Brønsted acid. H2 evolution from the Ni-based catalyst system can be maintained for over 60 h, demonstrating that the combination is a promising approach to improve the lifetimes of molecular catalysts towards photochemical H2 production. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2133 / 2138
页数：6
相关论文
共 48 条
  • [1] Boron-Capped Tris(glyoximato) Cobalt Clathrochelate as a Precursor for the Electrodeposition of Nanoparticles Catalyzing H2 Evolution in Water
    Anxolabehere-Mallart, Elodie
    Costentin, Cyrille
    Fournier, Maxime
    Nowak, Sophie
    Robert, Marc
    Saveant, Jean-Michel
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (14) : 6104 - 6107
  • [2] Artero V., 2011, ANGEW CHEM, V123, P7376, DOI [DOI 10.1002/ANIE.201007987, DOI 10.1002/ange.201007987]
  • [3] Splitting Water with Cobalt
    Artero, Vincent
    Chavarot-Kerlidou, Murielle
    Fontecave, Marc
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) : 7238 - 7266
  • [4] Solar Energy Supply and Storage for the Legacy and Non legacy Worlds
    Cook, Timothy R.
    Dogutan, Dilek K.
    Reece, Steven Y.
    Surendranath, Yogesh
    Teets, Thomas S.
    Nocera, Daniel G.
    [J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6474 - 6502
  • [5] Kinetics of Electron Transfer Reactions of H2-Evolving Cobalt Diglyoxime Catalysts
    Dempsey, Jillian L.
    Winkler, Jay R.
    Gray, Harry B.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) : 1060 - 1065
  • [6] Promoting Effect of Electrostatic Interaction between a Cobalt Catalyst and a Xanthene Dye on Visible-Light-Driven Electron Transfer and Hydrogen Production
    Dong, Jingfeng
    Wang, Mei
    Zhang, Pan
    Yang, Songqiu
    Liu, Jianyong
    Li, Xueqiang
    Sun, Licheng
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (30) : 15089 - 15096
  • [7] Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges
    Du, Pingwu
    Eisenberg, Richard
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (03) : 6012 - 6021
  • [8] Duortail G., 1977, BIOPOLYMERS, V16, P1397
  • [9] Discovery and high-throughput screening of heteroleptic iridium complexes for photoinduced hydrogen production
    Goldsmith, JI
    Hudson, WR
    Lowry, MS
    Anderson, TH
    Bernhard, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) : 7502 - 7510
  • [10] Visible light induced photopolymerization: speeding up the rate of polymerization by using co-initiators in dye/amine photoinitiating systems
    Grotzinger, C
    Burget, D
    Jacques, P
    Fouassier, JP
    [J]. POLYMER, 2003, 44 (13) : 3671 - 3677
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