Mild and Selective C(CO)-C(α) Bond Activation of Ketones with Rhodium(III) Porphyrin β-Hydroxyethyl

被引：11
|
作者：
Chan, Chung Sum [1 ]
Lee, Siu Yin [1 ]
Chan, Kin Shing [1 ]
机构：
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 01期
关键词：
CLEAVAGE; REACTIVITY; COMPLEX; ARENE;
D O I：
10.1021/om3009519
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rhodium(III) porphyrin beta-hydroxyethyl, Rh-III(ttp)CH2CH2OH (ttp = 5,10,15,20-tetratolylporphyrinato dianion), was found to serve as a precursor of the highly reactive Rh-III(ttp)OH for the C(CO)-C(alpha) bond activation (CCA) of ketones under mild and aerobic conditions of 25-50 degrees C.
引用
收藏
页码：151 / 156
页数：6
相关论文
共 50 条
  • [41] Selective Synthesis of Isoquinolines by Rhodium(III)-Catalyzed C-H/N-H Functionalization with α-Substituted Ketones
    Li, Jie
    Zhang, Zhao
    Tang, Mengyao
    Zhang, Xiaolei
    Jin, Jian
    ORGANIC LETTERS, 2016, 18 (15) : 3898 - 3901
  • [42] Rhodium-Catalyzed Hiyama Coupling Reaction of Unstrained Ketones via C-C Bond Cleavage
    Jiang, Cheng
    Wu, Wen-Qiang
    Lu, Hong
    Yu, Tian-Yang
    Xu, Wen-Hua
    Wei, Hao
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 8 (08) : 1358 - 1362
  • [43] A Highly Selective Amidation of Azoxybenzenes with Sulfonamides via Rhodium(III)-Catalyzed C-H Activation
    Li, Hongji
    Deng, Hong
    SYNTHESIS-STUTTGART, 2017, 49 (12): : 2711 - 2720
  • [44] K2CO3-Promoted Consecutive Carbon-Hydrogen and Carbon-Carbon Bond Activation of Cycloheptane with Rhodium(III) Porphyrin Complexes: Formation of Rhodium Porphyrin Cycloheptyl and Benzyl
    Chan, Kin Shing
    Chan, Yun Wai
    ORGANOMETALLICS, 2014, 33 (14) : 3702 - 3708
  • [45] Initial Stages in the Rhodium(III)-Catalyzed C-H Bond Activation of Primary Alcohols in Aqueous Solution
    Eriksen, Jette
    Monsted, Lene
    Monsted, Ole
    Olsen, Carl Erik
    Schaffer, Susan J. Cline
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (31) : 4938 - 4944
  • [46] Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation
    Colby, Denise A.
    Bergman, Robert G.
    Ellman, Jonathan A.
    CHEMICAL REVIEWS, 2010, 110 (02) : 624 - 655
  • [47] Rhodium(III)-Catalyzed Oxidative Annulation of Amidines with Alkynes via Sequential C-H Bond Activation
    Meng, Yan-Yu
    Zhu, Wen-Jing
    Song, Yuan-Yuan
    Bu, Gang-Gang
    Zhang, Li-Juan
    Xu, Fen
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (08) : 1290 - 1294
  • [48] Rhodium(III)-Catalyzed Addition of Indoles with Boc-Imines via C-H Bond Activation
    Wang, Jinfang
    Wang, Hui
    Yue, Chuanjun
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2018, 29 (06) : 1175 - 1182
  • [49] An efficient C-C bond formation reaction for the synthesis of α-arylated ketones under mild conditions
    Liu, Yanli
    Zhang, Xinhai
    Ma, Ying
    Ma, Chen
    TETRAHEDRON LETTERS, 2013, 54 (05) : 402 - 405
  • [50] C-H and C-O bond activation with a rhodium(I) β-diiminate complex
    Langer, Nicolle N. P.
    Bindra, Gurmeet Singh
    Budzelaar, Peter H. M.
    DALTON TRANSACTIONS, 2014, 43 (29) : 11286 - 11294
12345