Mild and Selective C(CO)-C(α) Bond Activation of Ketones with Rhodium(III) Porphyrin β-Hydroxyethyl

被引：11
|
作者：
Chan, Chung Sum [1 ]
Lee, Siu Yin [1 ]
Chan, Kin Shing [1 ]
机构：
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 01期
关键词：
CLEAVAGE; REACTIVITY; COMPLEX; ARENE;
D O I：
10.1021/om3009519
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rhodium(III) porphyrin beta-hydroxyethyl, Rh-III(ttp)CH2CH2OH (ttp = 5,10,15,20-tetratolylporphyrinato dianion), was found to serve as a precursor of the highly reactive Rh-III(ttp)OH for the C(CO)-C(alpha) bond activation (CCA) of ketones under mild and aerobic conditions of 25-50 degrees C.
引用
收藏
页码：151 / 156
页数：6
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