NMR and EPR Spectroscopy Applied to Homogeneous Catalysis

被引：1
|
作者：
Talzi, E. P. [1 ,2 ]
Brylyakov, K. P. [1 ,2 ]
Lyakin, O. Yu. [1 ,2 ]
Zima, A. M. [1 ,2 ]
Soshnikov, I. E. [1 ,2 ]
机构：
[1] Novosibirsk State Univ, Novosibirsk 630090, Russia
[2] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
来源：
KINETICS AND CATALYSIS | 2015年 / 56卷 / 04期
基金：
俄罗斯科学基金会;
关键词：
NMR spectroscopy; EPR spectroscopy; homogeneous catalysis; active sites of catalysts; olefin epoxidation; olefin polymerization; NONHEME IRON; ETHYLENE POLYMERIZATION; ZIEGLER-NATTA; H-2; NMR; C-H; H2O2; ACTIVATION; EPOXIDATION; FE; HYDROXYLATION;
D O I：
10.1134/S0023158415040175
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The article deals with applying NMR and EPR spectroscopy to the study of the active sites of catalysts in two important classes of reactions: enantioselective olefin epoxidation with hydrogen peroxide catalyzed by iron aminopyridine complexes and olefin polymerization in the presence of titanium and vanadium post-metallocene catalysts.
引用
收藏
页码：484 / 492
页数：9
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