Vapor pressure of ethanol plus benzyltributylammonium chloride solution and vapor-liquid equilibrium of ethanol plus water plus benzyltributylammonium chloride mixture at atmospheric pressure

被引:12
|
作者
Lee, LS [1 ]
Huang, MY [1 ]
Hsu, HL [1 ]
机构
[1] Natl Cent Univ, Dept Chem Engn, Chungli 32054, Taiwan
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D O I
10.1021/je980188q
中图分类号
O414.1 [热力学];
学科分类号
摘要
In this study, the vapor pressures of benzyltributylammonium chloride and ethanol solutions were measured from 298.25 K to 318.15 K, and the enthalpies of vaporization of this mixture were estimated by the Clausius-Clapeyron equation. The vapor-liquid equilibria of the ethanol and water mixtures with 2 m and saturated concentrations of the same organic salt were measured with an Othmer type equilibrium cell under atmospheric pressure. The uncertainty of the calibration is +/-0.0019 mole fraction for the water + ethanol mixture and that of temperature is 0.1 K.
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页码:528 / 531
页数:4
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