Synthesis, Spectroscopic Characterization and Antitumoral Activities of Cyclopentadienylvanadium Derivatives of Polyoxotungstates

被引：4

作者：

Liu Ju-tao ^{[1
]}

Lu Yan-fei ^{[1
]}

Fan Sheng-di ^{[1
]}

机构：

[1] Dalian Nationalities Univ, Coll Life Sci, Dalian 116600, Peoples R China

来源：

SPECTROSCOPY AND SPECTRAL ANALYSIS | 2012年 / 32卷 / 09期

关键词：

Polyoxotungstate; Cyclopentadienylvanadium derivatives; Supported; Incorporated; Organometallic complexes; Antitumoral activities;

D O I：

10.3964/j.issn.1000-0593(2012)09-2512-03

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Cyclopentadienylvanadium derivatives of polyoxotungstates [Bu4N](4) [(CpV)1pW(11)O(39)] (1), [Bu4H[(CpV)SiW11 O-39] (2) and [Bu4N](4)[A-beta-(eta(5)-CpV)SiW9V3O40] (3) were synthesized, and characterized by elemental analysis, IR, V-51 and l"W NMR spectroscopy. Experiment results indicate that (1) and (2) are polyoxometalate-incorporated organometallic complexes, and (3) is a polyoxometalate supported organometallic complex. Antitumoral activities were examined by MIT method. Experiment results indicate that the title complexes did exhibit to a certainty antitumor activity for HL-60 and B-16.

引用

页码：2512 / 2514

页数：3

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