The effect of the perturbation of hydrogen bonding on the Zn(II) coordination geometry:: synthesis and structure of [Zn(BIP) (H2O)2] (ClO4)2 (BIP=1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propane)

被引：7
|
作者：
Long, LS [1 ]
Chen, XM [1 ]
Ji, LN [1 ]
机构：
[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 05期
基金：
中国国家自然科学基金;
关键词：
crystal structures; hydrogen bonding; 1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propane; coordination geometry;
D O I：
10.1016/S1387-7003(99)00042-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A polydentate ligand comprising imidazole donor 1,3-bis[( 4-methyl-5-imidazol-1-yl) ethylideneamino] propane (BIP) was synthesized, and the crystal structure of its Zn(II) complex [Zn(BIP)(H2O2)(2)] (ClO4)(2) has been reported, in which the Zn(II) atom adopts a distorted octahedral coordination geometry with the equatorial positions occupied by four nitrogen atoms of BIP and the axial positions by two aqua molecules, The effect of hydrogen bonding of the aqua ligand on the coordination geometry is discussed. (C) 1999 Elsevier Science S.A. All rights reserved.
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页码：181 / 183
页数：3
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