Two Iron Complexes as Homogeneous and Heterogeneous Catalysts for the Chemical Fixation of Carbon Dioxide

被引：28

作者：

Karan, Chandan Kumar ^{[1
]}

Bhattacharjee, Manish ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 08期

关键词：

METAL-ORGANIC FRAMEWORK; CYCLIC CARBONATES; CO2; CYCLOADDITION; EFFICIENT; EPOXIDES; CAPTURE; COORDINATION; AROMATICITY; CONVERSION;

D O I：

10.1021/acs.inorgchem.8b00379

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new bimetallic iron-alkali metal complexes of amino acid (serine)-based reduced Schiff base ligand were synthesized and structurally characterized. Their efficacy as catalysts for the chemical fixation of carbon dioxide was explored. The heterogeneous version of the catalytic reaction was developed by the immobilization of these homogeneous bimetallic iron-alkali metal complexes in an anion-exchange resin. The resin-bound complexes can be used as recyclable catalysts up to six cycles.

引用

页码：4649 / 4656

页数：8

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