Heterogeneous visible light photocatalysis for selective organic transformations

被引:1355
作者
Lang, Xianjun [1 ]
Chen, Xiaodong [1 ]
Zhao, Jincai [2 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore
[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
基金
新加坡国家研究基金会;
关键词
SUPPORTED GOLD NANOPARTICLES; METAL-FREE OXIDATION; DYE-SENSITIZED TIO2; AEROBIC OXIDATION; CARBON NITRIDE; EFFICIENT CONVERSION; ALLOY NANOPARTICLES; CATALYTIC-OXIDATION; AROMATIC ALCOHOLS; HIGHLY EFFICIENT;
D O I
10.1039/c3cs60188a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The future development of chemistry entails environmentally friendly and energy sustainable alternatives for organic transformations. Visible light photocatalysis can address these challenges, as reflected by recent intensive scientific endeavours to this end. This review covers state-of-the-art accomplishments in visible-light-induced selective organic transformations by heterogeneous photocatalysis. The discussion comprises three sections based on the photocatalyst type: metal oxides such as TiO2, Nb2O5 and ZnO; plasmonic photocatalysts like nanostructured Au, Ag or Cu supported on metal oxides; and polymeric graphitic carbon nitride. Finally, recent strides in bridging the gap between photocatalysis and other areas of catalysis will be highlighted with the aim of overcoming the existing limitations of photocatalysis by developing more creative synthetic methodologies.
引用
收藏
页码:473 / 486
页数:14
相关论文
共 62 条
[1]   Photochemical Reactions as Key Steps in Natural Product Synthesis [J].
Bach, Thorsten ;
Hehn, Joerg P. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (05) :1000-1045
[2]   Visible-light-driven oxidation of organic contaminants in air with gold nanoparticle catalysts on oxide supports [J].
Chen, Xi ;
Zhu, Huai-Yong ;
Zhao, Jin-Cai ;
Zheng, Zhan-Feng ;
Gao, Xue-Ping .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (29) :5353-5356
[3]   Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light [J].
Chen, Xiufang ;
Zhang, Jinshui ;
Fu, Xianzhi ;
Antonietti, Markus ;
Wang, Xinchen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (33) :11658-+
[4]  
Christopher P, 2011, NAT CHEM, V3, P467, DOI [10.1038/NCHEM.1032, 10.1038/nchem.1032]
[5]   Urea derivatives enhance the photocatalytic activity of dye-modified titanium dioxide [J].
Fueldner, Stefan ;
Mitkina, Tatiana ;
Trottmann, Tobias ;
Frimberger, Alexandra ;
Gruber, Michael ;
Koenig, Burkhard .
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2011, 10 (04) :623-625
[6]   Green-light photocatalytic reduction using dye-sensitized TiO2 and transition metal nanoparticles [J].
Fueldner, Stefan ;
Mild, Ralph ;
Siegmund, Heiko Ingo ;
Schroeder, Josef A. ;
Gruber, Michael ;
Koenig, Burkhard .
GREEN CHEMISTRY, 2010, 12 (03) :400-406
[7]   Photocatalytic Oxidation of Alcohols over TiO2 Covered with Nb2O5 [J].
Furukawa, Shinya ;
Shishido, Tetsuya ;
Teramura, Kentaro ;
Tanaka, Tsunehiro .
ACS CATALYSIS, 2012, 2 (01) :175-179
[8]   Rapid one-pot propargylamine synthesis by plasmon mediated catalysis with gold nanoparticles on ZnO under ambient conditions [J].
Gonzalez-Bejar, Maria ;
Peters, Kate ;
Hallett-Tapley, Geniece L. ;
Grenier, Michel ;
Scaiano, Juan C. .
CHEMICAL COMMUNICATIONS, 2013, 49 (17) :1732-1734
[9]   Plasmon-Mediated Catalytic Oxidation of sec-Phenethyl and Benzyl Alcohols [J].
Hallett-Tapley, Geniece L. ;
Silvero, M. Jazmin ;
Gonzalez-Bejar, Maria ;
Grenier, Michel ;
Netto-Ferreira, Jose Carlos ;
Scaiano, Juan C. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (21) :10784-10790
[10]   Characteristics of the charge transfer surface complex on titanium(IV) dioxide for the visible light induced chemo-selective oxidation of benzyl alcohol [J].
Higashimoto, Shinya ;
Okada, Kohei ;
Azuma, Masashi ;
Ohue, Hiroyoshi ;
Terai, Tadamasa ;
Sakata, Yoshihisa .
RSC ADVANCES, 2012, 2 (02) :669-676