Photoinduced magnetization of a cobalt-iron cyanide

被引：1698
作者：
Sato, O
Iyoda, T
Fujishima, A
Hashimoto, K
机构：
[1] UNIV TOKYO,DEPT APPL CHEM,BUNKYO KU,TOKYO 113,JAPAN
[2] KANAGAWA ACAD SCI & TECHNOL,TOKYO INST POLYTECH,ATSUGI,KANAGAWA 24302,JAPAN
来源：
SCIENCE | 1996年 / 272卷 / 5262期
关键词：
D O I：
10.1126/science.272.5262.704
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Photoinduced magnetization was observed in a Prussian blue analog, K0.2Co1-4[Fe(CN)(6)]. 6.9H(2)O. An increase in the critical temperature from 16 to 19 kelvin was observed as a result of red light illumination, Moreover, the magnetization in the ferrimagnetic region below 16 kelvin was substantially increased after illumination and could be restored almost to its original level by thermal treatment, These effects are thought to be caused by an internal photochemical redox reaction, Furthermore, blue light illumination could be used to partly remove the enhancement of the magnetization. Such control over magnetic properties by optical stimuli may have application in magneto-optical devices.
引用
收藏
页码：704 / 705
页数：2
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